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arXiv · 0710.5540

Fluctuation-driven heterogeneous chemical processes

Christiane M. Losert-Valiente Kroon·Ian J. Ford
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Abstract

We explore a new framework for describing the kinetics of a heterogeneous chemical reaction where two particles of the same chemical species form a reaction product of another chemical species on the surface of a seed particle. Traditional treatments neglect the effect of statistical fluctuations in populations. We employ techniques in a manner analogous to the treatment of quantum systems to develop a stochastic description of processes beyond the mean field approximation.

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Christiane M. Losert-Valiente Kroon, Ian J. Ford. 2007-10-29. Fluctuation-driven heterogeneous chemical processes. https://arxiv.org/abs/0710.5540

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