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arXiv · 0809.3736

Electric dipole rovibrational transitions in HD molecule

Krzysztof Pachucki·Jacek Komasa
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Abstract

The rovibrational electric dipole transitions in the ground electronic state of the HD molecule are studied. A simple, yet rigorous formula is derived for the transition rates in terms of the electric dipole moment function $D(R)$, which is calculated in a wide range of $R$. Our numerical results for transition rates are in moderate agreement with experiments and previous calculations, but are at least an order of magnitude more accurate.

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Krzysztof Pachucki, Jacek Komasa. 2008-09-22. Electric dipole rovibrational transitions in HD molecule. https://doi.org/10.1103/physreva.78.052503

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