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arXiv · 0811.2140

Hund's paradox and the collisional stabilization of chiral molecules

Johannes Trost·Klaus Hornberger
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Abstract

We identify the dominant collisional decoherence mechanism which serves to stabilize and super-select the configuration states of chiral molecules. A high-energy description of this effect is compared to the results of the exact molecular scattering problem, obtained by solving the coupled-channel equations. It allows to predict the experimental conditions for observing the collisional suppression of the tunneling dynamics between the left-handed and the right-handed configuration of D2S2 molecules.

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Johannes Trost, Klaus Hornberger. 2009-07-17. Hund's paradox and the collisional stabilization of chiral molecules. https://doi.org/10.1103/physrevlett.103.023202

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