The mixed chemistry phenomenon in Galactic Bulge PNe

Abstract

We investigate the dual-dust chemistry (DDC) phenomenon in PNe and discuss reasons for its occurrence, by analyzing Spitzer/IRS spectra of a sample of 40 Galactic PNe among which 26 belong to the Galactic Bulge (GB). The mixed chemistry is derived from the simultaneous detection of PAH features in the 6-14 micron range and crystalline silicates (CS) beyond 20 microns in the Spitzer/IRS spectra. Out of the 26 PNe observed in the GB, 21 show signatures of DDC. Our observations reveal that the simultaneous presence of O- and C-rich dust features in the IR spectra of [WC]-type PNe is not restricted to late/cool [WC]-type stars, as previously suggested in the literature, but is a common feature associated with all [WC]-type PNe. Surprisingly, we found that the DDC is seen also in all observed wels, as well as in other PNe with central stars being neither [WC] nor wels. Most sources observed display CS features in their spectra, with only a few PNe exhibiting, in addition, amorphous silicate bands. We appear to detect a recent change of chemistry at the end of the AGB evolution in the low-mass, high-metallicity population of GB PNe observed. The deficit of C-rich AGB stars in this environment suggests that the process of PAH formation in PNe occurs at the very end of the AGB phase. In addition, the population of low-mass, O-rich AGB stars in the GB, do not exhibit CS features in their spectra. Thus, the high detection rate of DDC that we find cannot be explained by long-lived O-rich (primordial or circumbinary) disks. Our most plausible scenario is a final thermal pulse on the AGB (or just after), which could produce enhanced mass loss, capable of removing/mixing (sometimes completely) the remaining H-rich envelope and exposing the internal C-rich layers, and generating shocks responsible for the silicate crystallization.