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arXiv · 0902.3797

Coherent bimolecular reactions with quantum-degenerate matter waves

H. Jing·J. Cheng·P. Meystre
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Abstract

We demonstrate theoretically that the abstraction reaction $A+B_2 \to AB+B$ can be driven coherently and efficiently with quantum-degenerate bosonic or fermionic matter waves. We show that the initial stages of the reaction are dominated by quantum fluctuations, resulting in the appearance of macroscopic non-classical correlations in the final atomic and molecular fields. The dynamics associated with the creation of bosonic and of fermionic dimer-atom pairs are also compared. This study opens up a promising new regime of quantum degenerate matter-wave chemistry.

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H. Jing, J. Cheng, P. Meystre. 2009-02-22. Coherent bimolecular reactions with quantum-degenerate matter waves. https://doi.org/10.1103/physreva.79.023622

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