Towards a large deviation theory for statistical-mechanical complex systems

Abstract

The theory of large deviations constitutes a mathematical cornerstone in the foundations of Boltzmann-Gibbs statistical mechanics, based on the additive entropy $S_{BG}=- k_B\sum_{i=1}^W p_i \ln p_i$. Its optimization under appropriate constraints yields the celebrated BG weight $e^{-βE_i}$. An elementary large-deviation connection is provided by $N$ independent binary variables, which, in the $N\to\infty$ limit yields a Gaussian distribution. The probability of having $n \ne N/2$ out of $N$ throws is governed by the exponential decay $e^{-N r}$, where the rate function $r$ is directly related to the relative BG entropy. To deal with a wide class of complex systems, nonextensive statistical mechanics has been proposed, based on the nonadditive entropy $S_q=k_B\frac{1- \sum_{i=1}^W p_i^q}{q-1}$ ($q \in {\cal R}; \,S_1=S_{BG}$). Its optimization yields the generalized weight $e_q^{-β_q E_i}$ ($e_q^z \equiv [1+(1-q)z]^{1/(1-q)};\,e_1^z=e^z)$. We numerically study large deviations for a strongly correlated model which depends on the indices $Q \in [1,2)$ and $γ\in (0,1)$. This model provides, in the $N\to\infty$ limit ($\forall γ$), $Q$-Gaussian distributions, ubiquitously observed in nature ($Q\to 1$ recovers the independent binary model). We show that its corresponding large deviations are governed by $e_q^{-N r_q}$ ($\propto 1/N^{1/(q-1)}$ if $q>1$) where $q= \frac{Q-1}{γ(3-Q)}+1 \ge 1$. This $q$-generalized illustration opens wide the door towards a desirable large-deviation foundation of nonextensive statistical mechanics.