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arXiv · 1202.1908

13C NMR study of superconductivity near charge instability realized in beta"-(BEDT-TTF)4[(H3O)Ga(C2O4)3]C6H5NO2

Yoshihiko Ihara·Harumi Seki·Atsushi Kawamoto
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Abstract

To investigate the superconducting (SC) state near a charge instability, we performed ^{13}C NMR experiments on the molecular superconductor beta"-(BEDT-TTF)_{4}[(H_{3}O)Ga(C_{2}O_{4})_{3}]C_{6}H_{5}NO_{2}, which exhibits a charge anomaly at 100 K. The Knight shift which we measured in the SC state down to 1.5 K demonstrates that Cooper pairs are in spin-singlet state. Measurements of the nuclear spin-lattice relaxation time reveal strong electron-electron correlations in the normal state. The resistivity increase observed below 10 K indicates that the enhanced fluctuation has an electric origin. We discuss the possibility of charge-fluctuation-induced superconductivity.

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Yoshihiko Ihara, Harumi Seki, Atsushi Kawamoto. 2012-02-09. 13C NMR study of superconductivity near charge instability realized in beta"-(BEDT-TTF)4[(H3O)Ga(C2O4)3]C6H5NO2. https://doi.org/10.7566/jpsj.82.083701

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