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arXiv · 1208.2652

Absence of charge order in the dimerized κ-phase BEDT-TTF salts

Katrin Sedlmeier·Sebastian Elsasser·Rebecca Beyer·Dan Wu·Tomislav Ivek·Silvia Tomic·John A. Schlueter·Martin Dressel
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Abstract

Utilizing infrared vibrational spectroscopy we have investigated dimerized two-dimensional organic salts in order to search for possible charge redistribution that might cause electronic dipoles and ferroelectricity: the quantum spin liquid κ-(BEDT-TTF)2Cu2(CN)3, the antiferromagnetic Mott insulator κ-(BEDT-TTF)2$Cu[N(CN)2]Cl, and the superconductor κ-(BEDT-TTF)2$Cu[N(CN)2]Br. None of them exhibit any indication of charge disproportionation upon cooling down to low temperatures. No modification in the charge distribution is observed around T = 6 K where a low-temperature anomaly has been reported for the spin-liquid κ-(BEDT-TTF)2$Cu2(CN)3. In this compound the in-plane optical response and vibrational coupling are rather anisotropic, indicating that the tilt of the BEDT-TTF molecules in c-direction and their coupling to the anion layers has to be considered in the explanation of the electromagnetic properties.

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Katrin Sedlmeier, Sebastian Elsasser, Rebecca Beyer, Dan Wu, Tomislav Ivek, Silvia Tomic, John A. Schlueter, Martin Dressel. 2012-08-13. Absence of charge order in the dimerized κ-phase BEDT-TTF salts. https://doi.org/10.1103/physrevb.86.245103

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