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arXiv · 1301.5592

Solvent hydrodynamics speed up crystal nucleation in suspensions of hard spheres

Marc Radu·Tanja Schilling
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Abstract

We present a computer simulation study on the crystal nucleation process in suspensions of hard spheres, fully taking into account the solvent hydrodynamics. If the dynamics of collodial crystallization were purely diffusive, the crystal nucleation rate densities would drop as the inverse of the solvent viscosity. However, we observe that the nucleation rate densities do not scale in this way, but are enhanced at high viscosities. This effect might explain the large discrepancy between the nuclation rate densities obtained by simulation and experiment that have reported in the literature so far.

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Marc Radu, Tanja Schilling. 2013-01-23. Solvent hydrodynamics speed up crystal nucleation in suspensions of hard spheres. https://doi.org/10.1209/0295-5075/105/26001

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