arXiv · 1401.7394
Collective excitation of a short-range charge ordering in $θ$-$\mbox{(BEDT-TTF)}_2\mbox{CsZn(SCN)}_4$
Abstract
We find a characteristic low-energy peak structure located in the range of 100-300 cm$^{-1}$ in the optical conductivity spectra of a quasi-two-dimensional organic compound with a triangular lattice, $θ$-$\mbox{(BEDT-TTF)}_2\mbox{CsZn(SCN)}_4$, in which two different types of short-range charge orderings (COs) coexist. Upon lowering the temperature, the low-energy peak becomes significant and shifts to much lower frequencies only for the polarization of ${E \parallel a}$, in contrast to the other broad electronic bands in the mid-infrared region. On introducing disorder, the low-energy peak is strongly suppressed in comparison with the broad electronic bands. This result indicates that the low-energy peak is attributed to a collective excitation that originates from the short-range CO with a relatively long-period $3\times3$ pattern. The present results shed light on the understanding of the low-energy excitation in the glassy electronic state, where the charge degrees of freedom remain at low temperatures.
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K. Hashimoto, S. C. Zhan, R. Kobayashi, S. Iguchi, N. Yoneyama, T. Moriwaki, Y. Ikemoto, T. Sasaki. 2014-01-29. Collective excitation of a short-range charge ordering in $θ$-$\mbox{(BEDT-TTF)}_2\mbox{CsZn(SCN)}_4$. https://doi.org/10.1103/physrevb.89.085107
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