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arXiv · 1402.5401

Probing the structure and dynamics of molecular clusters using rotational wavepackets

Abstract

The chemical and physical properties of molecular clusters can heavily depend on their size, which makes them very attractive for the design of new materials with tailored properties. Deriving the structure and dynamics of clusters is therefore of major interest in science. Weakly bound clusters can be studied using conventional spectroscopic techniques, but the number of lines observed is often too small for a comprehensive structural analysis. Impulsive alignment generates rotational wavepackets, which provides simultaneous information on structure and dynamics, as has been demonstrated successfully for isolated molecules. Here, we apply this technique for the firsttime to clusters comprising of a molecule and a single helium atom. By forcing the population of high rotational levels in intense laser fields we demonstrate the generation of rich rotational line spectra for this system, establishing the highly delocalised structure and the coherence of rotational wavepacket propagation. Our findings enable studies of clusters of different sizes and complexity as well as incipient superfluidity effects using wavepacket methods.

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BibTeXRIS

Gediminas Galinis, Cephise Cacho, Richard T. Chapman, Andrew M. Ellis, Marius Lewerenz, Luis G. Mendoza Luna, Russell S. Minns, Mirjana Mladenovic, Arnaud Rouzée, Emma Springate, I. C. Edmond Turcu, Mark J. Watkins, Klaus von Haeften. 2014-02-21. Probing the structure and dynamics of molecular clusters using rotational wavepackets. https://doi.org/10.1103/physrevlett.113.043004

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