Induced cooperative motions in a medium driven at the nanoscale: Searching for an optimum excitation period

Abstract

Recent results have shown the appearance of induced cooperative motions called dynamic heterogeneity during the isomerization of diluted azobenzene molecules in a host glass-former. In this paper we raise the issue of the coupling between these "artificial" heterogeneities and the isomerization period. How do these induced heterogeneities differ in the saturation regime and in the linear response regime ? Is there a maximum of the heterogeneous motion versus isomerization rate and why ? Are the heterogeneity evolution with the isomerization rate connected with the diffusion or relaxation time evolution ? We use out of equilibrium molecular dynamics simulations to answer these questions. We find that the heterogeneity increases in the linear response regime for large isomerization periods and small perturbations. In contrast the heterogeneity decreases in the saturation regime, i.e. when the isomerization half-period ($τ_{p}/2$) is smaller than the relaxation time of the material ($τ_α$). This result makes possible a test of the effect of cooperative motions on the dynamics using the chromophores as Maxwell demons that destroy or stimulate the cooperative motions. Because the heterogeneities increase in the linear regime and then decrease in the saturation regime, we find a maximum for $τ_{p}/2 \approx τ_α$. The induced excitations concentration follows a power law evolution versus the isomerization rate and then saturates. As a consequence the $α$ relaxation time is related to the excitation concentration with a power law, a result in qualitative agreement with recent findings in constrained models. This result supports a common origin for the heterogeneities with constrained models and a similar relation to the excitation concentration.