Search arXivSearch

arXiv · 1406.6853

Inhomogeneous Thermal Conductivity Enhances Thermoelectric Cooling

Abstract

We theoretically investigate the enhancement of thermoelectric cooling performance in thermoelectric devices made of materials with inhomogeneous thermal conductivity, beyond the usual practice of enhancing thermoelectric figure of merit ZT. The dissipation of Joule heat in such thermoelectric devices is asymmetric which can give rise to better thermoelectric cooling performance. Although the thermoelectric figure of merit and the coefficient-of-performance are only slightly enhanced, both the maximum cooling power and the maximum cooling temperature difference can be enhanced significantly. This finding can be used to increase the heat absorption at the cold end. The asymmetric dissipation of Joule heat also leads to thermal rectification.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Tingyu Lu, Jun Zhou, Nianbei Li, Ronggui Yang, Baowen Li. 2014-06-26. Inhomogeneous Thermal Conductivity Enhances Thermoelectric Cooling. https://doi.org/10.1063/1.4903547

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

When blinking helps: enhanced single-photon purity in the off states of perovskite quantum dots

Photoluminescence blinking typically degrades the single-photon purity of quantum dot emission. Here, we show that individual CsPbBr$_3$ perovskite quantum dots (PQDs) can exhibit the opposite behavior: low-emitting off states are dimmer and shorter-lived, yet more strongly antibunched than high-intensity on states. Using time-correlated single-photon counting combined with state-resolved second-order correlation analysis, we identify a subset of PQDs in which the zero-delay second-order correlation, $g^{(2)}_0$, decreases upon switching from the on state to the off state, indicating improved single-photon purity. In the most pronounced case, $g^{(2)}_0$ decreases from 0.23 in the on state to 0.08 in the off state. We attribute this counterintuitive behavior to self-trapped-exciton-mediated suppression of the biexciton--exciton cascade, which suppresses multiphoton emission more effectively than single-exciton emission. These findings reveal an unconventional blinking regime in PQDs and show that blinking does not necessarily degrade single-photon purity.

cond-mat.mes-hall

Prediction of two-dimensional $π$-electron half-metallic ferrimagnets

We propose a strategy to obtain conducting organic materials with fully spin-polarized Fermi surface, lying at a singular flat band, with antiferromagnetically coupled magnetic moments that reside in pi-orbitals of nanographenes. We consider a honeycomb crystal whose unit cell combines two different molecules with $S=1/2$: an Aza-3-Triangulene, a molecule with orbital degeneracy, and a 2-Triangulene. The analyzed system is half-metallic with a ferrimagnetic order, presenting a zero net total magnetic moment per unit cell. We combine density functional theory calculations with a Hubbard model Hamiltonian to compute the magnetic interactions, the bands, the intrinsic Anomalous Hall effect, and the collective spin excitations. We obtain very large intermolecular exchange couplings, in the range of 59 meV. Based on the spin excitation dispersion, we estimate thermal stability in the range of 100 Kelvin. When the magnetization is off-plane, intrinsic spin orbit coupling in graphene opens up a topological gap that, despite being very small, leads to a quantized Hall conductance in the tens of mK range, but is thermally smeared above 1 Kelvin.

cond-mat.mes-hall

Analytical and numerical solutions to the non-diffusive Stefan problem

In this work, the Maxwell--Cattaneo--Vernotte (MCV) equation is used to model the one-dimensional hyperbolic Stefan problem in the limit of a small Stefan number (Ste $\ll$ 1). The solutions are approximated with perturbation series expansions using a reformulation in which time is expressed as a function of the solid-liquid interface position. The first proposed solution is derived in a framework that considers diffusive heat transfer at the phase change interface, for analytic tractability. Two rectification strategies are proposed to address the asymptotic divergence present in this formulation: a rescaled inner solution which is then combined with the outer solution to yield a composite solution, and size-dependent thermo-physical system parameters for better capture of hyperbolic effects at the phase change interface. The resulting interface profiles exhibit a characteristic parabolic-like shape, consistent with diffusive Stefan problem findings, with pronounced early-time hyperbolic effects at larger thermal relaxation times. Parametric studies are done over three pertinent variables in the dimensionless system: the Stefan number ($\mathrm{Ste}$), the dimensionless thermal relaxation time ($\widetilde τ$), and the thermal diffusivity ($α$). The studies suggest that model error scales with the Stefan number in accordance with the theoretical truncation error of the perturbation expansion. Additionally, larger values of $\widetilde τ$ amplify early-time hyperbolic effects, thereby increasing model error, while larger $α$ extends the relative temporal domain over which these hyperbolic effects remain significant, also corresponding to an increase in model error.

cond-mat.mes-hall