Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 1502.06849

Raman Spectroscopy of Electrochemically-Gated Graphene Transistors: Geometrical Capacitance, Electron-Phonon, Electron-Electron, and Electron-Defect Scattering

Guillaume Froehlicher·Stéphane Berciaud
View original source ↗Read source document ↗Export metadata ↓

Abstract

We report a comprehensive micro-Raman scattering study of electrochemically-gated graphene field-effect transistors. The geometrical capacitance of the electrochemical top-gates is accurately determined from dual-gated Raman measurements, allowing a quantitative analysis of the frequency, linewidth and integrated intensity of the main Raman features of graphene. The anomalous behavior observed for the G-mode phonon is in very good agreement with theoretical predictions and provides a measurement of the electron-phonon coupling constant for zone-center ($Γ$ point) optical phonons. In addition, the decrease of the integrated intensity of the 2D-mode feature with increasing doping, makes it possible to determine the electron-phonon coupling constant for near zone-edge (K and K' points) optical phonons. We find that the electron-phonon coupling strength at $Γ$ is five times weaker than at K (K'), in very good agreement with a direct measurement of the ratio of the integrated intensities of the resonant intra- (2D') and inter-valley (2D) Raman features. We also show that electrochemical reactions, occurring at large gate biases, can be harnessed to efficiently create defects in graphene, with concentrations up to approximately $1.4\times 10^{12}~\rm cm^{-2}$. At such defect concentrations, we estimate that the electron-defect scattering rate remains much smaller than the electron-phonon scattering rate. The evolution of the G- and 2D-mode features upon doping remain unaffected by the presence of defects and the doping dependence of the D mode closely follows that of its two-phonon (2D mode) overtone. Finally, the linewidth and frequency of the G-mode phonon as well as the frequencies of the G- and 2D-mode phonons in doped graphene follow sample-independent correlations that can be utilized for accurate estimations of the charge carrier density.

Explore related subjects

cond-mat.mes-hall

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Guillaume Froehlicher, Stéphane Berciaud. 2015-04-16. Raman Spectroscopy of Electrochemically-Gated Graphene Transistors: Geometrical Capacitance, Electron-Phonon, Electron-Electron, and Electron-Defect Scattering. https://doi.org/10.1103/physrevb.91.205413

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Inverse Purcell Suppression of Decoherence in Majorana Qubits via Environmental Engineering

We show that the electromagnetic or phononic environment of a topological quantum device can be engineered to actively suppress decoherence. For a Majorana qubit in a superconducting wire, the exponentially small splitting $ε\sim e^{-L/ξ}$ that provides topological protection also makes the qubit vulnerable to low-frequency noise. From a microscopic local interaction, we derive the effective low-energy coupling between the Majorana parity operator and a bosonic field; the coupling strength itself is proportional to $ε$, reflecting the qubit's non-local nature. The resulting pure-dephasing rate scales as $Γ_ϕ\propto ε^2 S(ε)$, with $S(ε)$ the environmental noise power at frequency $ε$. In the experimentally relevant high-temperature regime ($k_B T \gtrsim \hbarε$), this gives $Γ_ϕ\propto ερ(ε) T$, where $ρ(ε)$ is the environmental density of states. By engineering an environment with a suppressed low-frequency density of states, $ρ_{\text{eng}}(ω) = ρ_0 (ω/ω_c)^α$ for $ω< ω_c$ ($α> 0$), the dephasing rate drops to $Γ_ϕ^{\text{eng}} \propto ε^{α+1} \propto e^{-(α+1)L/ξ}$. Thus, longer wires yield exponentially better coherence---a direct synergy with topological protection. This "inverse Purcell" effect, which suppresses the density of states at the qubit frequency, provides a quantitative design principle for environmental engineering. Our work establishes spectral density shaping as a practical method for enhancing coherence in topological quantum devices.

cond-mat.mes-hall↗
arXiv2026

Axionic tunneling from a topological Kondo insulator

Discoveries over the past two decades have revealed the remarkable ability of quantum materials to emulate relativistic properties of the vacuum, from Dirac cones in graphene to Dirac surface states of topological insulators. Yet one of the most elusive consequences of topology in quantum matter -- the axionic ${\bf E}\cdot{\bf B}$ contribution to the electromagnetic response, predicted to produce strong magnetoelectric effects -- remains experimentally challenging to detect. Here we report evidence for an axion-like magnetoelectric response obtained through scanning tunneling microscopy (STM) using a SmB$_6$ nanowire tip on an antiferromagnetic Fe$_{1+x}$Te sample. Our measurements reveal a striking voltage-induced magnetization: millivolt biases generate measurable tip magnetizations that reverse with the voltage. The magnitude, tunability, and reversibility of this signal are consistent with an axion-like ${\bf E} \cdot {\bf B}$ coupling, which naturally accounts for the voltage-odd magnetic component of the tip spectral function while strongly constraining a conventional static-magnetism interpretation. Moreover, millivolt-scale control of spin polarization in a tunnel junction provides a new route for probing axionic electrodynamics and opens avenues for future STM and spintronic applications.

cond-mat.mes-hall↗
arXiv2026

Exciton-mediated optical control of liquid-solid friction

Interfacial friction in nanofluidic systems can arise from fluctuation-induced coupling between liquid charge fluctuations and the internal excitations of the confining solid. Here, we develop a microscopic theory of exciton-mediated solid-liquid friction based on the coupling between optically generated excitons and charge fluctuations in water. We distinguish between static excitons, localized by disorder or functionalization, and dynamic excitons, which interact with water through polarization fluctuations. In both cases, we derive analytical formulas for the excitonic friction, which is experimentally tunable and can significantly reduce the slip length and thereby the hydraulic permeability of nanochannels. Applying our framework to carbon nanotubes, we quantitatively reproduce the recent measurements of Kistwal et al., showing a reduction of nanotube diffusion under optical excitation, without fitting parameters. More broadly, our results establish excitons as a mechanism to optically control nanofluidic transport and suggest that excitonic photoluminescence could provide an optical probe of flow velocity inside nanochannels.

cond-mat.mes-hall↗