Search arXivSearch

arXiv · 1508.07365

Effects of discretization on viscosity in the necklace model

Abstract

The consequences of discretization on the resulting viscosity for the necklace model are analyzed to find out the mechanisms by which this model leads to results different from what could be anticipated. In order to accomplish this, various models of increasing complexity are proposed. First, the effects of the jump distance and temporal discretizations are studied. Then, the lack of proportionality between the length and the mass of the chains and the fact that chains do not perform a random walk are analyzed. Knowing of these influences on the viscosity, we finally address the effect of length fluctuations. It is shown that fluctuations can have unexpected effects that lead to larger or smaller values of viscosity. The simplicity of the studied models allows us to quantify the effects of discretization and fluctuations, effects that can be present in other models of similar or larger complexity.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

D. A. Mártin, C. M. Aldao. 2015-08-28. Effects of discretization on viscosity in the necklace model. https://doi.org/10.1016/j.physa.2009.11.005

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

The free energy of the square lattice Ising model with interactions alternating in horizontal and vertical directions

The free energy of the Ising model on the square lattice with alternating interactions in both horizontal and vertical directions is exactly derived. This model is distinct from the checkerboard Ising model. The result includes Onsager's free energy as a special case, and also includes Lee-Yang's free energy with an imaginary field, and relates these two solutions via continuous parameters. The result includes a generalization of Lee-Yang's result to cases with four different couplings. It is also derived that each imaginary magnetic field $iπ/2$ applied to a lattice site corresponds to a single frustrated square in its dual lattice.

cond-mat.stat-mech

Ideal heat engine cycles at maximal efficiency -- the ideal gas and beyond

Given a particular heat engine cycle, what is the optimal working medium that results in the highest efficiency? While one might jump to the conclusion that it must surely be the ideal gas, the situation is actually more intricate. Starting with a general Helmholtz potential that depends polynomially on molar volume and temperature we derive exact expressions for the ideal Stirling, Otto, and Brayton cycles. We find that for the thermodynamic systems described by our ansatz for the Helmholtz potential the maximal efficiency is achieved, if the working medium is described by a fundamental relation linear in temperature. This includes the ideal gas, but also classical harmonic oscillators and phenomenological models of the rubber band.

cond-mat.stat-mech

Local Detailed Balance in the Lorenz Model: Replaces the Butterfly with Frenetic Bursting

The Lorenz system is the canonical low-order model of convective instability, yet its dissipative and driving terms have never been checked against, nor constructed from, an explicit thermodynamic bookkeeping. We derive a modification that satisfies the local-detailed-balance condition for macroscopic relaxation toward nonequilibrium steady states, thereby identifying the thermodynamic force, entropy-production rate and frenesy of the resulting flow. The resulting model produces a transition from a quiescent fixed point to a robust, large-amplitude relaxation oscillation, closely analogous to recharge-discharge oscillator paradigms used for the El Nino-Southern Oscillation. The system alternates between a long, nearly reversible recharge phase and a brief, violently frenetic discharge burst, during which essentially all of the cycle's activity and entropy production is concentrated.

cond-mat.stat-mech