Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 1510.05619

Minimal physical requirements for crystal growth self-poisoning

Stephen Whitelam·Yuba Raj Dahal·Jeremy D. Schmit
View original source ↗Read source document ↗Export metadata ↓

Abstract

Self-poisoning is a kinetic trap that can impair or prevent crystal growth in a wide variety of physical settings. Here we use dynamic mean-field theory and computer simulation to argue that poisoning is ubiquitous because its emergence requires only the notion that a molecule can bind in two (or more) ways to a crystal; that those ways are not energetically equivalent; and that the associated binding events occur with sufficiently unequal probability. If these conditions are met then the steady-state growth rate is in general a non-monotonic function of the thermodynamic driving force for crystal growth, which is the characteristic of poisoning. Our results also indicate that relatively small changes of system parameters could be used to induce recovery from poisoning.

Explore related subjects

cond-mat.stat-mechcond-mat.soft

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Stephen Whitelam, Yuba Raj Dahal, Jeremy D. Schmit. 2016-01-04. Minimal physical requirements for crystal growth self-poisoning. https://doi.org/10.1063/1.4941457

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Direct Experimental Test of Conformal Invariance via Grazing Scattering: A Proposal for X-ray and Neutron Experiments

We propose a test of conformal invariance in critical phenomena based on the study of a two-point correlation function in the presence of a boundary. This two-point function can be studied using X-ray or neutron scattering in the conditions of total reflection (so-called grazing scattering). The conformal Ward identity in momentum space is here expressed as a differential constraint on the scattering cross-section, as a function of the momentum transfer and the scattering angle. Experimental verification using X-rays and binary alloys appears well within the existing techniques, while feasibility for neutron scattering requires further study. This would be the first direct experimental test of conformal invariance in critical phenomena, a symmetry widely assumed but never directly verified.

cond-mat.stat-mech↗
arXiv2026

Thermodynamic and statistical properties of a multifractional modified dispersion relation via the grand-canonical ensemble

We study the thermodynamic and statistical properties of a gas governed by a multifractional modified dispersion relation of the form $ω^{2}=k^{2}+4E_{*}^{-1/2}k^{5/2}$, where $E_{*}$ sets the characteristic scale of the multifractional correction. Working within the grand-canonical ensemble, we derive the modified density of states, the grand potential, the partition function, and the main thermodynamic quantities for both bosonic and fermionic sectors. The deformation changes the available phase-space distribution and produces nonstandard thermal scalings controlled by the ratio $T/E_{*}$. In the infrared regime, the usual relativistic gas behavior is recovered with leading corrections proportional to powers of $(T/E_{*})^{1/2}$. In the ultraviolet regime, the density of states scales as $\varrho(ω)\propto ω^{7/5}$, corresponding to an effective density-of-states dimension $d_{\mathrm{eff}}=12/5$. As a consequence, the Stefan-Boltzmann law is deformed from $u\propto T^{4}$ to $u\propto E_{*}^{3/5}T^{17/5}$, while the equation-of-state parameter approaches $w=5/12$ instead of the standard radiation value $w=1/3$. We also analyze thermal stability, particle number and energy fluctuations, Bose-Einstein condensation, and the degenerate Fermi gas limit. The multifractional correction increases the critical temperature of a conserved bosonic gas and modifies the Fermi energy, pressure, sound speed, and low-temperature heat capacity of degenerate fermions. A direct fit to the COBE/FIRAS monopole spectrum yields $E_{*}>0.36\,\mathrm{MeV}$ at $95\%$ CL, while the conservative GWTC--3 propagation constraint gives $E_{*}>1.18\times10^{19}\,\mathrm{GeV}$ at $90\%$ credibility when the dispersion relation is assumed to be universal.

cond-mat.stat-mech↗
arXiv2026

Foundations of Many-Body Theory of Quantum Unified Statistics: Green functions and Linear Response Theory

We develop a comprehensive many-body theory for systems of particles obeying quantum unified statistics, or quons. After exploring the properties of the Fock space of this system, we formulate a systematic S-matrix expansion and a generalized Wick's theorem. A consistent Green-function formalism is constructed at both zero and finite temperatures, accompanied by a generalized Wick's theorem appropriate for infinite-statistics operator algebras. Within this framework, we establish diagrammatic rules for interacting quon systems. Employing the random phase approximation, we derive the dielectric function and reveal the emergence of anomalous plasmon modes that have no direct counterpart in conventional Bose or Fermi systems. We further analyze the ground-state energy, energy-loss function, generalized Thomas-Fermi screening wave vectors, and Friedel oscillations, elucidating how infinite statistics qualitatively modifies collective behavior and screening properties.

cond-mat.stat-mech↗