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arXiv · 1709.05909

Hydrophobic-hydrophilic interactions drive rapid nanoparticle assembly

Benjamin F. Porter·Mercè Pacios·Harish Bhaskaran
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Abstract

The unique physical and optical properties of nanoparticles make their reliable and rapid assembly an important goal for nanotechnology. To this end, many competing driving forces have been targeted to control the self-assembly, though issues with reliability and efficiency indicate that interfaces on the nanoscale are not yet fully understood. In this letter we report for the first time that the flow of water media from the interface between chemically nanopatterned hydrophobic surfaces and adjacent hydrophilic regions (a Janus interface) can effectively be employed for rapid nanoparticle assembly with single nanoparticle resolution. We find that the dewetting of water molecules from this Janus interface drives the assembly of nanoparticles from electrostatically stabilised nanoparticle colloids onto the hydrophobic areas, expedited by removing the resistance to adhesion between wetted interfaces exerted by any hydration barrier, such that nanoparticle assembly is achieved in under a minute. We call this method of controlled nanoparticle assembly Janus Interface Nanoparticle Assembly - JINA. We then demonstrate control of this mechanism through pH switching and prove its effectiveness for fabrication by rapidly creating single-nanoparticle sites and single particle wide lines whilst simultaneously densely coating macro-scale features. Not only does this assembly method have far-reaching implications in nanomanufacturing, the unanticipated nature of this mechanism also challenges many commonly held assumptions about the interfacial interactions of nanoparticle self-assembly.

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Benjamin F. Porter, Mercè Pacios, Harish Bhaskaran. 2017-09-18. Hydrophobic-hydrophilic interactions drive rapid nanoparticle assembly. https://arxiv.org/abs/1709.05909

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