Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 1711.10148

Electron paramagnetic resonance spectroscopy using a single artificial atom

Hiraku Toida·Yuichiro Matsuzaki·Kosuke Kakuyanagi·Xiaobo Zhu·William J. Munro·Hiroshi Yamaguchi·Shiro Saito
View original source ↗Read source document ↗Export metadata ↓

Abstract

Electron paramagnetic resonance (EPR) spectroscopy is an important technology in physics, chemistry, materials science, and biology. Sensitive detection with a small sample volume is a key objective in these areas, because it is crucial, for example, for the readout of a highly packed spin based quantum memory or the detection of unlabeled metalloproteins in a single cell. In conventional EPR spectrometers, the energy transfer from the spins to the cavity at a Purcell enhanced rate plays an essential role and requires the spins to be resonant with the cavity, however the size of the cavity (limited by the wavelength) makes it difficult to improve the spatial resolution. Here, we demonstrate a novel EPR spectrometer using a single artificial atom as a sensitive detector of spin magnetization. The artificial atom, a superconducting flux qubit, provides advantages both in terms of its quantum properties and its much stronger coupling with magnetic fields. We have achieved a sensitivity of $\sim$400 spins/$\sqrt{\mathrm{Hz}}$ with a magnetic sensing volume around $10^{-14} λ^3$ (50 femto-liters). This corresponds to an improvement of two-order of magnitude in the magnetic sensing volume compared with the best cavity based spectrometers while maintaining a similar sensitivity as those spectrometers . Our artificial atom is suitable for scaling down and thus paves the way for measuring single spins on the nanometer scale.

Explore related subjects

quant-ph

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Hiraku Toida, Yuichiro Matsuzaki, Kosuke Kakuyanagi, Xiaobo Zhu, William J. Munro, Hiroshi Yamaguchi, Shiro Saito. 2017-11-28. Electron paramagnetic resonance spectroscopy using a single artificial atom. https://doi.org/10.1038/s42005-019-0133-9

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Enhanced measurements on quantum computers via the simultaneous probing of non-commuting Pauli operators

Measuring the state of quantum computers is a highly non-trivial task, with implications for virtually all quantum algorithms. A promising avenue is multi-copy schemes, where identical copies of a quantum state are measured jointly so that all Pauli operators within the considered observable can be simultaneously assessed. Here, we present a first implementation of such a two-copy scheme in a measurement protocol. Based on Bayesian statistics, it accurately estimates not only the average of the desired observable but also the error en route. This enables an adaptive shot-allocation algorithm that preferentially samples the most uncertain Pauli terms. In regimes with many non-commuting Pauli operators, this ``double'' scheme can outperform the state-of-the-art measurement protocol in minimizing total shots for a given precision. We also numerically confirm the finding in previous theoretical works that the two-copy scheme incurs an overhead due to the square-root relationship between the variance of measured quantities and the number of measurement shots.

quant-ph↗
arXiv2026

Thermodynamics of a phaseonium-driven optomechanical Otto engine

We study an optomechanical Otto engine whose working medium is a single-mode cavity driven by beams of coherently prepared three-level phaseonium atoms. The atoms are not thermal reservoirs in the Gibbs sense; rather, their populations and ground-state coherence set the detailed-balance ratio of the cavity collision map, so that the field relaxes to a Gibbs state at an operational apparent temperature. We combine the finite-time collision-model dynamics with radiation-pressure work extraction and compare three reservoir preparations: a thermal reference at the same apparent temperatures, an incoherent atomic beam with the same populations, and the coherent phaseonium beam. We show that the phaseonium isochore charges the cavity passively: the cavity ergotropy and energy-basis coherence remain zero up to numerical precision, while the state converges to the Gibbs fixed point selected by the apparent detailed balance. We further estimate lower bounds on the cost of preparing the atomic populations and coherence, showing that the relevant advantage of phaseonium is a resource-preparation tradeoff rather than a cost-free enhancement over a thermal bath at the same temperature. Finally, we assess the finite-time performance of a two-cavity cascade with additive mechanical work accounting. Over the investigated coherence-phase range, the cascade produces approximately $47\%$--$52\%$ more power than the single-cavity engine while requiring only $65\%$--$68\%$ of the hot and cold phaseonium atoms needed by two independent engines, resulting in a $9\%$--$15\%$ enhancement of power per injected atom over a complete cycle.

quant-ph↗
arXiv2026

Dynamical Correlation of the Post-quench Non-thermal Equilibrium State

After a quantum quench, the integrable system is expected to relax to a non-thermal equilibrium state (NTES) whose local properties are believed to be governed by a generalized Gibbs ensemble (GGE). Combining quench action and the form factor approach, we compute the field-field correlation in the NTES produced by an interaction quench of the Lieb-Liniger model. The spectral distribution is shown to be qualitatively different from that of a thermal equilibrium state (TES): a new dispersion branch appears whose microscopic mechanism can be traced to the algebraic decaying tail for the root density distribution function, and indicates the existence of a broader family of NTES featuring similar spectral property.

quant-ph↗