Search arXivSearch

arXiv · 1809.09140

Scattering of cold $^4$He on $^4$He$-^{6,7}$Li and $^4$He$-^{23}$Na molecules

Abstract

We predict $s-$wave elastic cross-sections $σ$ for low-energy atom-molecule collisions with kinetic energies up to 40 mK, for the $^4$He collision with weakly bound diatomic molecules formed by $^4$He with $^7$Li, $^6$Li and $^{23}$Na. Our scattering calculations are performed by using diatomic and triatomic molecular binding energies obtained from several available realistic models as input in a renormalized zero-range model, as well as a finite-range one-term separable potential in order to quantify the relevance of range corrections to our predictions. Of particular relevance for possible experimental realization, we show the occurrence of a zero in $σ$ for the collision of cold $^4$He on $^4$He$-^{23}$Na molecule below 20 mK. Also our results for the elastic collision $^4$He on $^4$He$-^{6,7}$Li molecules suggest that $σ$ varies considerably for the realistic models studied. As the chosen molecules are weakly bound and the scattering energies are very low, our results are interpreted on the light of the Efimov physics, which explains the model independent and robustness of our predictions, despite some sensitivity on the potential range.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

M. A. Shalchi, A. Delfino, T. Frederico, Lauro Tomio. 2018-09-24. Scattering of cold $^4$He on $^4$He$-^{6,7}$Li and $^4$He$-^{23}$Na molecules. https://doi.org/10.1103/physreva.98.032705

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Effective Conservation and Bistability of Atomic Alignment under Strong Spin~Exchange

We present a phenomenological model of anomalous alignment signals in dense cesium vapor under linearly polarized pumping and fast spin exchange near zero magnetic field. Despite the absence of a conservation law for rank-2 angular momentum, our recent experiments reveal anisotropic narrow resonances, hysteresis, and bistability. We attribute these effects to a stretched state forming a collective mode in which orientation and alignment are bidirectionally coupled. This mode acts as a reservoir, preserving the essential properties of alignment despite rapid spin exchange.

physics.atom-ph

$LS/LSJ$ Hybrid Coupling Framework for Auger Angular Distributions of Experimentally Unresolved Multiplets with Isolated Fine-Structure

We present a hybrid $LS/LSJ$ coupling framework for treating state multiplets in the regime $ΔE_\text{int}\sim\hbar/τ_\text{int} \ggΔE_\text{FS}\ggΓ$, where $τ_\text{int}$ is the collision interaction time, $ΔE_\text{FS}$ the fine-structure splitting, and $Γ$ the natural width. In this regime, the collision interaction is fast compared with fine-structure evolution, whereas the individual $J$ levels are well isolated on the scale of their natural widths. The produced multiplet's alignment is therefore described in $LS$ coupling and then projected onto the individual fine-structure $J$ levels before their subsequent decay, described by $LSJ$ coupling. Applied to the multi-open-shell $1s2s2p\,^4\!P_J$ manifold, which closely satisfies these conditions, the hybrid treatment reveals strong suppression and inversion of the Auger angular-distribution anisotropy relative to the traditional pure-$LS$ treatment. It substantially improves agreement with absolute experimental data while using the same $LS$ production cross sections. This hybrid $LS/LSJ$ framework thus provides the appropriate treatment of state multiplets with isolated fine-structure levels, as it retains the $J$-dependent decay dynamics missing from the traditional pure-$LS$ treatment.

physics.atom-ph

Optical Ion Clock with Engineered Immunity to Motion-Induced Frequency Shifts

Spectroscopic frequency shifts due to residual motion of the probed atoms significantly contribute to the uncertainty budgets of state-of-the-art optical ion clocks. For clock transitions with second-order Doppler and quadratic Stark shifts of opposite signs, it is possible to configure electrodynamic ion confinement such that these two shift effects become anticorrelated causing zero net shift. Here, we introduce a spectroscopic interrogation protocol which leads, for systems with unknown and varying motional energy gain rates, to first-order auto-suppression of corresponding frequency shifts without requiring the opposite-sign configuration. We experimentally demonstrate the proposed method on a new ytterbium ion optical clock probing the 467 nm electric octupole (E3) transition, where the combined fractional uncertainty contribution from motion-induced frequency shifts is reduced from $1.3\times10^{-18}$ to $0.3\times10^{-18}$. An interleaved optical frequency ratio measurement against ytterbium's electric quadrupole transition (E2) at 435 nm delivers an E3/E2 frequency ratio of $0.932 \,829 \,404 \,530 \,965 \, 340 (39)$. Combined with previously published ratio data this leads to a limit for a potential fractional temporal variation of the fine-structure constant of $2.4 (2.7) \times 10^{-19}/$yr, in agreement with existing bounds.

physics.atom-ph