Observation of high-Tc superconductivity in inhomogeneous combinatorial ceramics

Mitra Iranmanesh; Nikolai D. Zhigadlo; Thanaporn Tohsophon; John R. Kirtley; Wilfried Assenmacher; Werner Mader; Jürg Hulliger

doi:10.1016/j.solidstatesciences.2018.12.003

arXiv · 1812.06273

Observation of high-Tc superconductivity in inhomogeneous combinatorial ceramics

Mitra Iranmanesh·Nikolai D. Zhigadlo·Thanaporn Tohsophon·John R. Kirtley·Wilfried Assenmacher·Werner Mader·Jürg Hulliger

View original source ↗Read source document ↗Export metadata ↓

Abstract

A single-sample synthesis concept based on multi-element ceramic samples can produce a variety of local products. When applied to cuprate superconductors (SC), statistical modelling predicts the occurrence of possible compounds in a concentration range of about 50 ppm. In samples with such low concentrations, determining which compositions are superconducting is a challenging task and requires local probes or separation techniques. Here, we report results from samples with seven components: BaO2, CaCO3, SrCO3, La2O3, PbCO3, ZrO2 and CuO oxides and carbonates, starting from different grain sizes. The reacted ceramics show different phases, particular grain growth, as well as variations in homogeneity and superconducting properties. High-Tc superconductivity up to 118 K was found. Powder x-ray diffraction (XRD) in combination with energy-dispersive spectroscopy (EDS), scanning transmission electron microscopy (STEM) can assign Pb1223 and (Sr,Ca,Ba)0.7-1.0CuO2 phases in inhomogeneous samples milled with 10 mm ball sizes. Rather uniform samples featuring strong grain growth were obtained with 3 mm ball sizes, resulting in Tc =70 K superconductivity of the La(Ba,Ca)2Cu3Ox based phase. Scanning SQUID microscopy (SSM) establishes locally formed superconducting areas at a level of a few microns in inhomogeneous superconducting particles captured by a magnetic separation technique. The present results demonstrate a new synthetic approach for attaining high-Tc superconductivity in compounds without Bi, Tl, Hg, or the need for high-pressure synthesis.

Explore related subjects

cond-mat.supr-con

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Mitra Iranmanesh, Nikolai D. Zhigadlo, Thanaporn Tohsophon, John R. Kirtley, Wilfried Assenmacher, Werner Mader, Jürg Hulliger. 2018-12-15. Observation of high-Tc superconductivity in inhomogeneous combinatorial ceramics. https://doi.org/10.1016/j.solidstatesciences.2018.12.003

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Collective excitation-mediated transport in nanoscale Josephson junctions that exhibit quantum confinement

Quantum confinement can strongly modify transport through Josephson junctions. Here, we study local tunneling transport through nanoscale Josephson junction stacks in the Coulomb blockade regime, where the metallic layers exhibit strong vertical quantum confinement. We find that quasiparticle transport is strongly enhanced by a collective excitation mode intrinsic to the junction and localized in the isolated metallic overlayer. We quantify both the collective-mode energy and the Coulomb gap and show that both exhibit strong layer-dependent modulation, consistent with the modulation of the underlying quantum well states. We further investigate how the collective excitation responds to various perturbations, including mechanical motion and an applied magnetic field. Our results suggest that this collective mode is sensitive to quasiparticles near the Fermi level and may therefore provide an indirect probe of the superconducting state.

cond-mat.supr-con↗

arXiv2026

Universal Dzyaloshinski-Moriya interaction dictates pairing in unconventional superconductor families

The collinear-antiferromagnetic spin-fluctuation paradigm has long guided unconventional superconductivity research, yet fails to reconcile the noncollinear spin phenomena observed across cuprates, iron-based superconductors, and nickelates. Using extensive first-principles calculations and unbiased large-scale DMRG simulations, we show that Dzyaloshinski-Moriya interaction (DMI)-arising from local inversion-symmetry breaking-is a common ingredient across these families. This DMI unifies hallmark observations in parent compounds-incommensurate orders, spin-wave gaps, and noncollinear textures. Under hole doping, strong DMI drives spin vortices to merge with pi-shifted hole stripes, forming hybrid vortex-hole stripe phases. These phases stabilize charge order while supporting, not suppressing, superconductivity. By contrast, under electron doping, these vortices pin holes and suppress long-range superconductivity. Our results establish DMI as a unifying link between noncollinear magnetism and superconductivity, identifying hole-strip-vortex coupling as a microscopic pairing engine. Given that DMI is common across major superconductor families, these findings challenge the prevailing pairing mechanism and offer an experimentally testable roadmap for materials optimization.

cond-mat.supr-con↗

arXiv2026

Digital-analog concept for superconducting perceptron-like neural networks

A promising route to superconducting artificial neural networks is a hybrid digital-Analog architecture that combines digital single-flux-quantum (SFQ) communication with compact Analog nonlinear processing. The study focused on the dynamic conversion of a discrete signal passing through a digital-to-Analog-to-digital (DAD) converter, in which the role of the Analog cell was performed by a $Σ$-neuron with a nonlinear transfer function -- the basic cell of perceptron-like neural networks. Furthermore, the DAD converter, the elementary functional block of the hybrid architecture, combines a digital-to-analog converter (DAC) and an Analog-to-digital converter (ADC), and re-encodes the Analog $Σ$-neuron waveforms as an SFQ pulse sequence. Circuit-level simulations demonstrate how input values encoded by SFQ pulse trains are converted into analog signal levels, transformed by the $Σ$-neuron, and mapped back to pulse-based outputs. As a key experimental step, we fabricated and characterised a redesigned $Σ$-neuron and measured a sigmoid-like transfer characteristic suitable for activation-function implementation. The extracted response was incorporated into system-level simulations to assess the influence of realistic device parameters on the conversion process. We delineate the operating-range matching requirements for the DAC, neuron, and ADC blocks, supporting the feasibility of the proposed interface as a building block for perceptron-like superconducting neural networks with digital inputs and outputs. Finally, we developed two perceptron networks, one using a mathematical sigmoid activation and the other the measured $Σ$-neuron transfer characteristic, which reached classification accuracies of $97.0\%$ and $91.9\%$, respectively, on the MNIST handwritten digit dataset.

cond-mat.supr-con↗