Statics and Dynamics of Polymeric Droplets on Chemically Homogeneous and Heterogeneous Substrates

Abstract

We present a molecular dynamics study of the motion of cylindrical polymer droplets on striped surfaces. We first consider the equilibrium properties of droplets on different surfaces, we show that for small stripes the Cassie-Baxter equation gives a good approximation of the equilibrium contact angle. As the stripe width becomes non-negligible compared to the dimension of the droplets, the droplet has to deform significantly to minimize its free energy, this results in a smaller value of the contact angle than the continuum model predicts. We then evaluate the slip length, and thus the damping coefficient as a function of the stripe width. For very small stripes, the heterogeneous surface behaves as an effective surface, with the same damping as an homogeneous surface with the same contact angle. However, as the stripe width increases, damping at the surface increases until reaching a plateau. Afterwards, we study the dynamics of droplets under a bulk force. We show that if the stripes are large enough the droplets are pinned until a critical acceleration. The critical acceleration increases linearly with stripe width. For large enough accelerations, the average velocity increases linearly with the acceleration, we show that it can then be predicted by a model depending only the size of droplet, viscosity and slip length. We show that the velocity of the droplet varies sinusoidally as a function of its position on the substrate. On the other hand, for accelerations just above the depinning acceleration we observe a characteristic stick-slip motion, with successive pinnings and depinnings.