Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 1906.07650

Classifying hydrogen-rich superconductors

Evgueni F. Talantsev
View original source ↗Read source document ↗Export metadata ↓

Abstract

The era of near-room-temperature superconductivity started after experimental discovery by Drozdov et al (2015 Nature 525 73) who found that compressed H3S exhibits superconducting transition at Tc = 203 K. To date, the record near-room-temperature superconductivity stands with another hydrogen-rich highly compressed compound, LaH10 (Somayazulu et al 2019 Phys. Rev. Lett. 122 027001), which has critical temperature of Tc>240 K. In this paper, we analyse available upper critical field, Bc2(T), data for LaH10 (Drozdov et al 2019 Nature 569 528) and report that this compound in all considered scenarios has the ratio of Tc to the Fermi temperature, Tf, 0.009 < Tc/Tf < 0.038, which is typical range for unconventional superconductors. In attempt to extend our finding, we examined experimental Bc2(T) data for superconductors in the palladium-hydrogen (PdHx) and thorium-hydrogen-deiterium (ThH-ThD) systems and surprisingly find that superconductors in both these systems also fall into unconventional superconductors band. Taking in account that H3S has the ratio of 0.012 < Tc/Tf < 0.039 (Talantsev 2019 Mod. Phys. Lett. B 33 1950195) we come to conclusion that in the Uemura plot all discovered to date hydrogen-rich superconductors, i.e., Th4H15-Th4D15, PdHx, H3S and LaH10 (in this list we do not include NbTiHx, PtHx, SiH4, and PH3 for which experimental data beyond Tc are unknown), lie in same band as all unconventional superconductors, particularly heavy fermions, fullerenes, pnictides, and cuprates, and former should be classified as a new class of unconventional superconductors.

Explore related subjects

cond-mat.supr-concond-mat.str-el

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Evgueni F. Talantsev. 2019-07-25. Classifying hydrogen-rich superconductors. https://doi.org/10.1088/2053-1591%2Fab3bbb

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Superconductivity in MgHCu3 perovskite revisited

We reexamine the crystal structure, electronic structure, lattice dynamics, phonon dispersion, electron-phonon coupling, and superconducting properties of MgHCu3 perovskite using the PBEsol and PBE functionals. This perovskite phase was recently proposed to exhibit superconductivity with the critical superconducting temperature, TC, of 42 K, which falls slightly over the classical 40 K limit for the phonon driven superconductivity. We show that although the crystal and electronic structure of this hypothetical compound are quite robust with respect to the k point mesh and functional used, yet the phonons and phonon related properties are extremely sensitive to the density of the grid chosen as well as functional used for calculations. Correspondingly, the values of the critical superconducting temperature calculated here for different Gaussian broadenings vary in a broad range of ca. 10 to 31 K and they do not exceed the classical limit. We suggest that the properties of this and many other high TC hydrides claimed should be thoroughly scrutinized using a variety of functionals, and benchmarked with experiment, to provide more reliable values of TC.

cond-mat.supr-con↗
arXiv2026

Multigap superconductivity in Ising superconductors: The case of (LaSe)1.14(NbSe2)m misfit layer compounds

Strong spin-orbit coupling and broken inversion symmetry in transition metal dichalcogenides give rise to Ising superconductivity, a spin-protected pairing state first identified in monolayer NbSe$_2$ through in-plane critical fields far exceeding the Pauli limit. More recently, Ising superconductivity has been proposed as a potential route to unconventional and even topological superconductivity in bulk misfit compounds. Here, we investigate the superconducting order parameter of layered misfit compounds composed of alternating transition metal dichalcogenide and rocksalt layers, which host extremely doped, electronically decoupled NbSe$_2$ sheets within a three-dimensional crystal. Using directional scanning tunneling spectroscopy on the misfit superconductors (LaSe)$_{1.14}$(NbSe$_2$) and (LaSe)$_{1.14}$(NbSe$_2$)$_2$, we uncover a strongly anisotropic multigap superconducting state: a fragile gap on the $Γ$-centered Fermi-surface pocket coexists with a robust, intrinsic gap on the K and K$'$ pockets. These features are in quantitative agreement with momentum-resolved gaps $Δ(\mathbf{k})$ obtained from anisotropic Migdal-Eliashberg calculations. The marked fragility of the $Γ$-centered gap, combined with the strong sensitivity of the critical temperature to non-magnetic disorder, points to pairing beyond conventional $s$-wave symmetry, potentially involving a topological order parameter. These results establish NbSe$_2$-based misfit compounds as a tunable bulk platform for multigap, unconventional superconductivity, with Ising protection offering a promising route toward topological pairing.

cond-mat.supr-con↗
arXiv2026

Different reconstruction pathways toward superconductivity in TaRhTe4 and TaIrTe4 Weyl semimetals

Pressure can drive Weyl semimetals toward superconductivity through qualitatively distinct reconstructions of their lattices and normal-state electronic structures. Here, we report the first observation of superconductivity in compressed TaRhTe4. This finding enables a direct comparison of the distinct reconstruction pathways leading to superconductivity in TaRhTe4 and the previously studied TaIrTe4, both of which belong to the TaXTe4 (X = Rh, Ir) family of type-II Weyl semimetals. For TaRhTe4, high-pressure electrical-resistance, Hall effect, and magnetoresistance measurements, together with synchrotron X-ray diffraction and first-principles calculations, reveal a superconducting transition that emerges near 20 GPa, with onset Tc increasing to approximately 2.6 K at 65.2 GPa and zero resistance achieved above 63 GPa. The onset of superconductivity coincides with a progressive lattice distortion, a strong suppression of the positive magnetoresistance, and a continuous decrease of the Hall coefficient toward zero. Calculations further show that additional electron-like bands cross the Fermi level (EF) and that N(EF) increases upon compression. This evolution contrasts with TaIrTe4, where the Hall coefficient initially increases before reversing its pressure dependence near the superconducting threshold, while the structural anomaly is confined to a narrower pressure interval. This comparison indicates that superconductivity in the TaXTe4 family is not tied to a unique critical pressure or a single Fermi-surface reconstruction, but can emerge through distinct material-specific pathways once pressure sufficiently reconstructs the low-carrier Weyl-semimetal-derived state into a multiband metallic regime.

cond-mat.supr-con↗