The Density Matrix Renormalization Group in Chemistry and Molecular Physics: Recent Developments and New Challenges

Alberto Baiardi; Markus Reiher

doi:10.1063/1.5129672

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arXiv · 1910.00137

The Density Matrix Renormalization Group in Chemistry and Molecular Physics: Recent Developments and New Challenges

Alberto Baiardi·Markus Reiher

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Abstract

In the past two decades, the density matrix renormalization group (DMRG) has emerged as an innovative new method in quantum chemistry relying on a theoretical framework very different from that of traditional electronic structure approaches. The development of the quantum chemical DMRG has been remarkably fast: it has already become one of the reference approaches for large-scale multiconfigurational calculations. This perspective discusses the major features of DMRG, highlighting its strengths and weaknesses also in comparison to other novel approaches. The method is presented following its historical development, starting from its original formulation up to its most recent applications. Possible routes to recover dynamical correlation are discussed in detail. Emerging new fields of applications of DMRG are explored, in particular its time-dependent formulation and the application to vibrational spectroscopy.

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Alberto Baiardi, Markus Reiher. 2020-01-20. The Density Matrix Renormalization Group in Chemistry and Molecular Physics: Recent Developments and New Challenges. https://doi.org/10.1063/1.5129672

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