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arXiv · 2002.12101

Kramer doublets, phonons, crystal-field excitations and their coupling in Nd2ZnIrO6

Birender Singh·M. Vogl·S. Wurmehl·S. Aswartham·B. Büchner·Pradeep Kumar
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Abstract

We report comprehensive Raman-scattering measurements on a single crystal of double-perovskite Nd2ZnIrO6 in temperature range of 4-330 K, and spanning a broad spectral range from 20 cm-1 to 5500 cm-1. The paper focuses on lattice vibrations and electronic transitions involving Kramers doublets of the rare-earth Nd3+ ion with local C1 site symmetry. Temperature evolution of these quasi-particle excitations have allowed us to ascertain the intricate coupling between lattice and electronic degrees of freedom in Nd2ZnIrO6. Strong coupling between phonons and crystal-field excitation is observed via renormalization of the self-energy parameter of the phonons i.e. peak frequency and line-width. The phonon frequency shows abrupt hardening and line-width narrowing below ~ 100 K for the majority of the observed first-order phonons. We observed splitting of the lowest Kramers doublets of ground state (4I9/2) multiplets i.e. lifting of the Kramers degeneracy, prominently at low-temperature (below ~ 100 K), attributed to the Nd-Nd/Ir exchange interactions and the intricate coupling with the lattice degrees of freedom. The observed splitting is of the order of ~ 2-3 meV and is consistent with the estimated value. We also observed a large number of high-energy modes, 46 in total, attributed to the intra-configurational transitions between 4f3 levels of Nd3+ coupled to the phonons reflected in their anomalous temperature evolution.

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Birender Singh, M. Vogl, S. Wurmehl, S. Aswartham, B. Büchner, Pradeep Kumar. 2020-02-27. Kramer doublets, phonons, crystal-field excitations and their coupling in Nd2ZnIrO6. https://doi.org/10.1103/physrevresearch.2.023162

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