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arXiv · 2003.12102

Translationally cold trapped CCl+ reactions with acetylene (C2H2)

Katherine J. Catani·James Greenberg·Benjamin V. Saarel·Heather J. Lewandowski
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Abstract

Ion-neutral chemical reactions are important in several areas of chemistry, including in some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of CCl+ with C2H2 are measured and the main products include c-C3H2+ and l-C3H+, both relevant in extraterrestrial environments. Accurate branching ratios are obtained, which favor formation of c-C3H2+ over l-C3H+ by a factor of four. Measured rate constants are on the order of Langevin and complementary electronic structure calculations are used to aid in the interpretation of experimental results.

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Katherine J. Catani, James Greenberg, Benjamin V. Saarel, Heather J. Lewandowski. 2020-03-26. Translationally cold trapped CCl+ reactions with acetylene (C2H2). https://arxiv.org/abs/2003.12102

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