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arXiv · 2006.15448

Theoretical determination of polarizability and magnetic susceptibility of neon

Michał Lesiuk·Michał Przybytek·Bogumił Jeziorski
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Abstract

We report theoretical determination of the dipole polarizability of the neon atom, including its frequency dependence. Corrections for the relativistic, quantum electrodynamics, finite nuclear mass, and finite nuclear size effects are taken into account. We obtain the value $α_0=2.66080(36)$ for the static polarizability, and $α_2=2.850(7)$ and $α_4=4.932(14)$ for the first two polarizability dispersion coefficients (Cauchy moments); all values are in atomic units (a.u.). In the case of static polarizability, our result agrees with the best experimental determination [C. Gaiser and B. Fellmuth, Phys. Rev. Lett. 120, 123203 (2018)], but our estimated uncertainty is significantly larger. For the dispersion coefficients, the results obtained in this work appear to be the most accurate to date overall compared to published theoretical and experimental data. We also calculated the static magnetic susceptibility of the neon atom, needed to obtain the refractive index of gaseous neon. Our result, $χ_0 = -8.484(19) \cdot 10^{-5}$ a.u., is about 9% larger in absolute value than the recommended experimental value [CRC Handbook of Chemistry and Physics, CRC Press, 2019, p. 4-145].

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Michał Lesiuk, Michał Przybytek, Bogumił Jeziorski. 2021-01-26. Theoretical determination of polarizability and magnetic susceptibility of neon. https://doi.org/10.1103/physreva.102.052816

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