Determination of Dielectric Functions and Exciton Oscillator Strength of Two-Dimensional Hybrid Perovskites

Baokun Song; Jin Hou; Haonan Wang; Siraj Sidhik; Jinshui Miao; Honggang Gu; Huiqin Zhang; Shiyuan Liu; Zahra Fakhraai; Jacky Even; Jean-Christophe Blancon; Aditya D. Mohite; Deep Jariwala

arXiv · 2009.14812

Determination of Dielectric Functions and Exciton Oscillator Strength of Two-Dimensional Hybrid Perovskites

Baokun Song·Jin Hou·Haonan Wang·Siraj Sidhik·Jinshui Miao·Honggang Gu·Huiqin Zhang·Shiyuan Liu·Zahra Fakhraai·Jacky Even·Jean-Christophe Blancon·Aditya D. Mohite·Deep Jariwala

View original source ↗Read source document ↗Export metadata ↓

Abstract

Two-dimensional (2D) hybrid organic inorganic perovskite (HOIP) semiconductors have attracted widespread attention as a platform of next generation optoelectronic devices benefiting from their naturally occurring and tunable multiple quantum-well like (QW) structures, which enable a wide range of physical properties. Determining the intrinsic optical/electronic properties of 2D HOIPs is extremely important for further utility in photonic and optoelectronics devices. Here, we obtain the optical dielectric functions, complex refractive indices, and complex optical conductivities of both Ruddlesden-Popper (RP) and Dion-Jacobsen (DJ) phases of 2D HOIPs as a function of the perovskite QW thickness via spectroscopic ellipsometry over a broad energy range of 0.73 - 3.34 eV. We identify a series of feature peaks in the dielectric functions, and explain the evolution of ground state exciton peak with unit cell thickness and changing excitonic confinement. We observe extraordinary values of optical extinction and electric loss tangents at the primary excitonic resonances and provide their detailed comparison with other known excitonic materials. Our study is expected to lay foundation for understanding optical properties of pure phase 2D HOIPs, which will be helpful for the accurate modelling of their photonics and optoelectronic devices.

Explore related subjects

physics.app-ph physics.optics

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Baokun Song, Jin Hou, Haonan Wang, Siraj Sidhik, Jinshui Miao, Honggang Gu, Huiqin Zhang, Shiyuan Liu, Zahra Fakhraai, Jacky Even, Jean-Christophe Blancon, Aditya D. Mohite, Deep Jariwala. 2020-09-30. Determination of Dielectric Functions and Exciton Oscillator Strength of Two-Dimensional Hybrid Perovskites. https://arxiv.org/abs/2009.14812

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Pendellösung length-scale neutron and X-ray interferometry

Neutron and X-ray perfect-crystal interferometers (PCIs) are powerful platforms for studies of fundamental physics and phase-contrast imaging. Further enhancing several PCI capabilities requires reducing crystal blade thickness to the micron scale, which minimizes dynamical-diffraction image blur, permits operation in the pendellösung regime where blade thickness controls beam splitting, and reduces absorption for simultaneous neutron and X-ray operation. However, fabricating multiple crystal blades with identical micrometer-scale thicknesses over centimeter-scale areas remains a major challenge. Here, using a non-etching sub-micron fabrication technique, we demonstrate silicon triple-Laue interferometers with equal-blade-thicknesses of 110 $μ$m and 350 $μ$m, operated with both neutrons and X-rays. These devices are the thinnest PCIs realized to date, enabling a factor-of-six reduction in dynamical-diffraction beam spreading for improved phase-contrast imaging, while reaching the single pendellösung length regime in which crystal thickness provides an experimentally accessible control parameter for engineered quantum-optical beam splitting of plane-wave inputs. These results motivate multi-blade PCI designs utilizing identical half-pendellösung crystal lamellae that are proposed for neutron spin--orbit and electric dipole moment measurements.

physics.app-ph↗

arXiv2026

A State-Space Framework for trivial and Topological Metamaterial Stochastic Analysis

Topological phononic crystals and elastic metamaterials support edge states defined by global topological invariants, offering a route toward vibration-control and wave-guiding devices that remain functional in the presence of defects. However, manufacturing-induced spatial variability can perturb these invariants and compromise their robustness, making its quantification essential during design. In this work, we first demonstrate that a previously proposed linear time-varying (LTV) formulation is mathematically equivalent to the spectral element method based on transfer matrices for elementary rod, Saint-Venant shaft, and Euler-Bernoulli beam theories. The deterministic formulation is then extended to stochastic analyses through a stochastic linear time-varying (SLTV) framework. The proposed methodology combines Monte Carlo simulations with stochastic Fourier series and an analytical Karhunen--Loève expansion, providing closed-form stochastic fields and their derivatives required by the LTV formulation. The SLTV approach enables the computation of stochastic dispersion diagrams and forced responses of one-dimensional waveguides with arbitrarily varying geometry and mechanical properties. Because the LTV-based transition matrix isolates individual wavemodes without requiring the mode tracking needed by conventional eigenproblem-based formulations, the framework is particularly suited for evaluating topological invariants, specifically the Zak phase, and assessing the robustness of topological bands under spatial variability. Numerical results for rods, shafts, and Euler-Bernoulli beams demonstrate the applicability of the proposed framework as a unified methodology for deterministic and stochastic analyses of trivial and topological periodic waveguides under continuous spatial uncertainty.

physics.app-ph↗

arXiv2026

Low-loss phononic integrated circuits based on a silicon nitride-lithium niobate platform

Microwave-frequency acoustic waves in solids have emerged as a versatile platform for both classical and quantum applications. While phononic integrated devices and circuits are being developed on various material platforms, an ideal phononic integrated circuit (PnIC) platform should simultaneously support low-loss waveguide structures, high-quality-factor resonators, high-performance modulators, and efficient electromechanical transducers. Here, we establish a low-loss gigahertz-frequency PnIC platform based on patterned thin-film silicon nitride (SiN) on lithium niobate (LN) substrate. We develop low-loss PnIC building blocks including waveguides, directional couplers, and high-quality-factor (high-Q) ring resonators. As an application, we demonstrate a 1-GHz phononic oscillator based on a ring resonator, reaching a low phase noise of -159.0 dBc/Hz at a 100-kHz offset frequency. Our low-loss PnICs could meet the requirements in microwave acoustics, quantum phononics, and integrated hybrid systems combining phonons, photons, superconducting qubits, and solid-state defects.

physics.app-ph↗