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arXiv · 2102.11967

Sloppy Gear Mechanism for Coupled Stochastic Transportation: from anti-equilibrium flow to infinite selectivity

Chase Slowey·Zhiyue Lu
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Abstract

Non-equilibrium transportation of particles through a restricted space (such as porous media or narrow channels) significantly differs from free space. With a simple model of two types of particles competing to transport via a passive single-lane channel connecting two chemical baths, we find two dynamical modes of transportation -- the dud mode and the ratchet mode. At the ratchet mode, the gradient flow of one type of particle forces the other into a transient anti-equilibrium flow against its gradient. At the dud mode, the two types of particles both flow according to their gradients. This counter-intuitive non-equilibrium effect can be explained by a sloppy gear mechanism. In addition to the anti-gradient flow observed in the ratchet mode, we find that the non-equilibrium sloppy gear mechanism suppresses the flow of one particle while allowing the flow for the other. This mechanism provides a general theoretical framework to explain and design the selective transportation of particles via passive channels.

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Chase Slowey, Zhiyue Lu. 2021-02-23. Sloppy Gear Mechanism for Coupled Stochastic Transportation: from anti-equilibrium flow to infinite selectivity. https://doi.org/10.1103/physrevresearch.4.023234

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