Search arXivSearch

arXiv · 2105.15199

Rotational Coherence Times of Polar Molecules in Optical Tweezers

Abstract

Qubit coherence times are critical to the performance of any robust quantum computing platform. For quantum information processing using arrays of polar molecules, a key performance parameter is the molecular rotational coherence time. We report a 93(7) ms coherence time for rotational state qubits of laser cooled CaF molecules in optical tweezer traps, over an order of magnitude longer than previous systems. Inhomogeneous broadening due to the differential polarizability between the qubit states is suppressed by tuning the tweezer polarization and applied magnetic field to a "magic" angle. The coherence time is limited by the residual differential polarizability, implying improvement with further cooling. A single spin-echo pulse is able to extend the coherence time to nearly half a second. The measured coherence times demonstrate the potential of polar molecules as high fidelity qubits.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Sean Burchesky, Loic Anderegg, Yicheng Bao, Scarlett S. Yu, Eunmi Chae, Wolfgang Ketterle, Kang-Kuen Ni, John M. Doyle. 2021-05-31. Rotational Coherence Times of Polar Molecules in Optical Tweezers. https://doi.org/10.1103/physrevlett.127.123202

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

High-optical-depth, sub-Doppler-width absorption lines at telecom wavelengths in hot, optically driven rubidium vapor

Doppler broadening presents a major limitation for high-resolution spectroscopy and nonlinear optics in room-temperature atomic vapors. Here, we demonstrate the suppression of Doppler broadening accompanied by pronounced absorption on the upper transition of a three-level ladder system, achieved by dressing the intermediate state with a strong control field. As a concrete realization, we study a hot vapor of $^{87}$Rb where the lower transition is driven by a strong control field resonant with the D2 line at a wavelength of 780 nm, while a weak counter-propagating probe field at the telecom C-band wavelength of 1529 nm ($5P_{(3/2)}\leftrightarrow 4D_{(5/2)}$) interrogates the dressed states. We observe absorption features with a resonant optical depth of approximately 4 and a full width at half maximum of about 17 MHz. Remarkably, this corresponds to an order-of-magnitude reduction relative to the Doppler width, while the optical depth on the upper transition of the ladder scheme exceeds that of the Doppler-broadened lower transition. The measured spectra are in good agreement with theoretical modeling. Combining high optical density with sub-Doppler-width absorption lines typically requires laser-cooled atoms, while our approach profits from the experimental simplicity of a hot-vapor platform.

physics.atom-ph

A CSFG-based neural network basis-selection method for large-scale RCI calculations within GRASPG

We present a neural network (NN) basis-selection method for large-scale relativistic configuration interaction (RCI) calculations in GRASPG. The method employs configuration state function generators (CSFGs), each of which generates a set of configuration state functions (CSFs) with the same spin-angular couplings, as the basic selection units for the NN. A constant-orbital feature-elimination strategy removes feature channels whose values remain unchanged across the CSFG pool. The CSFG representation reduces the number of learning units processed by the NN by more than one order of magnitude, while constant-orbital feature elimination further reduces the dimensionality of the NN input. Combined with the high-performance GRASPG framework, the method improves the efficiency of both NN selection and subsequent RCI calculations, maintaining a balance between accuracy and computational cost. In a moderate Ni(12+) benchmark, where the corresponding full-space RCI calculation is still feasible, the CSFs generated by the retained CSFG sets reproduce the full-space RCI results at the few inverse-centimeter level for the target states. For the representative J = 0, even-parity block, the complete workflow reduces the wall time by 75.6 percent, and the peak memory required by a single RCI calculation is reduced by a factor of 10.1. In a larger-scale calculation with a full CSF expansion containing 1.27 x 10^9 CSFs, the method retains only 1.1-1.9 percent of the full-space CSFs and yields energy levels in good agreement with experimental data and other resource-intensive theoretical calculations.

physics.atom-ph

Low-energy positron scattering from metastable helium

Low-energy positron scattering from singlet and triplet metastable He($1s2s$) is investigated using the $R$-matrix propagation method in hyperspherical coordinates. Elastic and positronium-formation cross sections are reported, and near-threshold resonance structures are analyzed in terms of eigenphase sums and the time-delay matrix. For the triplet target, the calculated cross sections are in agreement with available convergent-close-coupling results and display the expected threshold behavior. Beyond the known $S$-wave features, Feshbach resonance series in higher partial waves extending up to highly excited atomic thresholds are systematically identified. The time-delay matrix further uncovers hidden resonances that produce obvious structures in the positronium-formation cross sections.

physics.atom-ph