Experimental and computational studies on the reactivity of methanimine radical cation (H$_2$CNH$^{+\cdot}$) and its isomer aminomethylene (HCNH$_2^{+\cdot}$) with C$_2$H$_2$

Abstract

Experimental and theoretical studies are presented on the reactivity of the radical cation isomers methanimine and aminomethylene with ethyne. Selective isomer generation is performed via dissociative photoionization of suitable neutral precursors and via direct photoionization of methanimine. Reactive cross sections and product branching ratios are measured as a function of photon and collision energies. Results are discussed in light of ab initio calculations of reaction mechanisms. The major channels, for both isomers, are due to H atom elimination from covalently bound adducts to give [C3NH4]+. Theoretical calculations show that while for the reaction of aminomethylene with acetylene any of the three lowest energy [C3NH4]+ isomers can form via barrierless and exothermic pathways, for the methanimine reagent the only barrierless pathway is the one leading to the production of protonated vinyl cyanide (CH2CHCNH+), a prototypical branched nitrile species that has been proposed as a likely intermediate in star forming regions and in the atmosphere of Titan. The astrochemical implications of the results are briefly addressed.