Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 2204.05090

Direct 3D observation and unraveling of electroconvection phenomena during concentration polarization at ion-exchange membranes

Felix Stockmeier·Michael Schatz·Malte Habermann·John Linkhorst·Ali Mani·Matthias Wessling
View original source ↗Read source document ↗Export metadata ↓

Abstract

A decade ago, two-dimensional microscopic flow visualization proved the theoretically predicted existence of electroconvection roles as well as their decisive role in destabilizing the concentration polarization layer at ion-selective fluid/membrane interfaces. Electroconvection induces chaotic flow vortices injecting volume having bulk concentration into the ion-depleted diffusion layer at the interface. Experimental quantification of these important flow patterns have so far only been carried out in 2D. Numerical direct simulations suggest 3D features, yet experimental proof is lacking. 3D simulations are also limited in covering extended spacial and temporal scales. This study presents a new comprehensive experimental method for the time-resolved recording of the 3D electroconvective velocity field near a cation-exchange membrane. For the first time, the spatio-temporal velocity field can be visualized in 3D at multiples of the overlimiting current density. In contrast to today's simulations, these experiments cover length and time scales typical for actual electrodialytic membrane processes. We visualize coherent vortex structures and reveal the changes in the velocity field and its statistics during the transition from vortex rolls to vortex rings with increasing current density. The transition is characterized by changes in the rotational direction, mean square velocity, and temporal energy spectrum with only little influence on the spatial spectrum. These findings indicate a more significant impact of EC's structural change on the mean square velocities and temporal spectra than on the spatial spectra. This knowledge is a prerequisite for engineering ion-selective surfaces that will enable the operation of electrically driven processes beyond the diffusion-limited Nernst regime.

Explore related subjects

physics.flu-dynphysics.app-ph

Keep this discovery

BibTeXRIS

Felix Stockmeier, Michael Schatz, Malte Habermann, John Linkhorst, Ali Mani, Matthias Wessling. 2022-04-11. Direct 3D observation and unraveling of electroconvection phenomena during concentration polarization at ion-exchange membranes. https://doi.org/10.1016/j.memsci.2021.119846

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Correlative effects of induced magnetic field-buoyancy on reactive solute dispersion dynamics in couple-stress fluids

We investigate the dispersion of a reactive solute in a couple-stress fluid flowing between two parallel plates under the combined effects of pressure-driven flow, buoyancy, and an induced magnetic field. The model incorporates first-order heterogeneous reactions at both channel walls alongside a bulk reaction. Using Mei's multiscale homogenization technique accurate to third order, we develop a higher-order asymptotic formulation to determine the effective longitudinal dispersion coefficient and concentration field. Analytical predictions are complemented by Brownian dynamics simulations and finite-difference solutions, while the Aris method of moments quantifies transient mean displacement, spatial variance, and effective dispersivity. The hydrodynamic analysis reveals a singular branch in the velocity solution when the Hartmann number equals half the couple-stress parameter and identifies a characteristic quarter-power scaling between the Hartmann number and couple-stress parameter, separating couple-stress- and magnetically dominated regimes. The model recovers classical Taylor-dispersion behavior in the non-reactive Newtonian limit and agrees well with experimental measurements. Couple-stress rheology and magnetic damping suppress shear-induced dispersion, whereas buoyancy enhances dispersion through additional transverse velocity gradients. A distinct saturation regime of the dispersion coefficient emerges with an increasing couple-stress parameter, while unequal wall absorption induces persistent transverse asymmetry, and stronger absorption enhances solute removal near the source. Numerical and stochastic results validate the analytical framework while resolving higher-order concentration structures and particle-scale wall adsorption.

physics.flu-dyn↗
arXiv2026

DiffSWE2d: a differentiable Shallow Water Equations solver for end-to-end flood and tsunami modelling

Solving inverse and optimisation problems with traditional shallow water equations (SWE) solvers can be computationally expensive, particularly when gradients with respect to model inputs or parameters must be estimated through repeated forward simulations. In this paper, we introduce DiffSWE2d, an open-source differentiable shallow water equations solver for end-to-end flood and tsunami modelling implemented in PyTorch. By leveraging automatic differentiation, DiffSWE2d represents the time-marching physics as a differentiable computational graph, enabling gradients to be propagated directly through the numerical solver. We validate the solver against two established benchmark cases and demonstrate its application to tsunami waveform inversion, showing its ability to infer model inputs through gradient-based optimisation. DiffSWE2d provides a flexible framework for integrating physics-based hydrodynamic modelling with modern optimisation and machine learning methods. The source code and reproducible examples are publicly available at: https://github.com/ZhonghouXu/DiffSWE2d

physics.flu-dyn↗
arXiv2026

Low inertia limit of elasto-inertial turbulence

Pipe and channel flows of viscoelastic fluids display chaotic dynamics at unusually low speeds, a phenomenon referred to as elasto-inertial turbulence, EIT. First reported in experiments a century ago, recent theoretical studies and model computations predict a variety of scenarios for the phenomenon's origin, ranging from hoop stress modes to center modes and to Tollmien-Schlichting waves. Lacking experimental confirmation, the relevant scenario in actual flows of polymer solutions remains unknown. We here determine the transition threshold of EIT in pipe experiments, covering three decades in elasticity number. Across this entire parameter range, the transition features center mode structures at onset. Eventually the instability diverges at a lower inertia (upper elasticity) limit, which is a robust signature of this center mode scenario. Finally, we report the first experimental observation of a traveling wave in viscoelastic pipe flow, and the sequences of localized structures found, are in excellent agreement with a center mode traveling wave, the "arrowhead" solution, discovered in model simulations.

physics.flu-dyn↗