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arXiv · 2210.09741

Spin-related electronic pathway through single molecule on Au(111)

Mingjun Zhong·Qimeng Wu·Liang Ma·Jie Li·Yifan Wang·Yansong Wang·Xin Li·Yajie Zhang·Jingtao Lü·Yongfeng Wang
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Abstract

Spin properties of organic molecules have attracted great interest for their potential applications in spintronic devices and quantum computing. Fe-tetraphenyl porphyrin (FeTPP) is of particular interest for its robust magnetic properties on metallic substrates. FeTPP is prepared in vacuum via on-surface synthesis. Molecular structure and spin-related transport properties are characterized by low-temperature scanning tunneling microscope and spectroscopy at 0.5 K. Density functional theory calculations are performed to understand molecular adsorption and spin distribution on Au(111). The molecular structure of FeTPP is distorted upon adsorption on the substrate. Spin excitations of FeTPP are observed on the Fe atom and high pyrrole groups in differential conductance spectra. The calculated spin density distribution indicates that the electron spin of FeTPP is mainly distributed on the Fe atom. The atomic transmission calculation indicates that electrons transport to substrate is mediated through Fe atom, when the tip is above the high pyrrole group.

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Mingjun Zhong, Qimeng Wu, Liang Ma, Jie Li, Yifan Wang, Yansong Wang, Xin Li, Yajie Zhang, Jingtao Lü, Yongfeng Wang. 2022-10-18. Spin-related electronic pathway through single molecule on Au(111). https://arxiv.org/abs/2210.09741

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