Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 2212.02803

Efficient electrical switching of exciton states for valley contrast manipulation in two-dimensional perovskite/monolayer WS2 heterostructures

Yingying Chen·Zeyi Liu·Junchao Hu·Junze Li·Wendian Yao·Dehui Li
View original source ↗Read source document ↗Export metadata ↓

Abstract

The coupled spin-valley physics in transition metal dichalcogenides (TMDs) endows exciton states with valley degrees of freedom, making them promising for valleytronic applications in TMDs monolayers and/or their heterostructures. Although the valley dynamics of intralayer and interlayer excitons (IXs) have been studied, efficient manipulation of valley pseudospins by switching exciton states remains elusive. Therefore, it is of great importance to effectively tune the exciton states to obtain practical valley polarization switches for valley encoding. Here, we demonstrate the electrical switching of exciton emission with highly variable valley polarization mediated by charged IXs (CIXs) in the heterostructure of monolayer WS2 and two-dimensional (2D) perovskite, irrespective of lattice constants, the rotational and translational alignment. The formation of IXs is identified by photoluminescence excitation (PLE) and photoluminescence (PL) studies, which can be further electrically tuned from positively charged to negatively charged depending on the electrostatic doping level of monolayer WS2. Importantly, we demonstrate an electrical switching from type two to type one band alignment, manifesting as a change in the PL profile from CIX to charged intralayer exciton emission. Such transition induces a large contrast in valley polarization between the two exciton states, enabling the reversible electrically regulated valley polarization switch with a maximum ON/OFF ratio of 15.8. Our study provides an alternative mechanism to achieve valley polarization switching with great simplicity for valleytronics and the electrical control of exciton species and associated valley-contrasting physics would further facilitate the development of optoelectronic and valleytronic devices

Explore related subjects

physics.app-ph

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Yingying Chen, Zeyi Liu, Junchao Hu, Junze Li, Wendian Yao, Dehui Li. 2022-12-06. Efficient electrical switching of exciton states for valley contrast manipulation in two-dimensional perovskite/monolayer WS2 heterostructures. https://arxiv.org/abs/2212.02803

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Hyperbolic dynamic friction models for viscoelastic sliding and rolling contact

This paper considers the sliding and rolling contact between viscoelastic bodies. Combining linear viscoelastic rheologies for bristle-like elements with nonlinear dynamic friction models, and under the assumption of small deformations and displacement gradients, it derives a class of viscoelasto-kinematic equations, formulated as a system of semilinear partial differential equations (PDEs) governing the evolution of the frictional force, bristle deformations, and internal state variables at the interface between the contacting bodies. The resulting system is analysed mathematically, demonstrating that linear viscoelasticity preserves the hyperbolic character of the PDE systems typically encountered in rolling contact. The proposed theory is illustrated through representative examples of both sliding and rolling contact, highlighting that these two processes, whilst often treated as distinct, may in fact exhibit closely related underlying dynamics. Overall, the framework provides a general theoretical setting applicable to a broad class of viscoelastic frictional systems.

physics.app-ph↗
arXiv2026

Teaching an LLM agent to fit XRR curves with X-Ray Calc 3

The structure of a periodic multilayer X-ray mirror is obtained by fitting its X-ray reflectivity (XRR) curve, and the result depends on how the operator normalizes and trims the curve, frees parameters, and accepts a fit. The manual of the fitting program and the papers describing its engine leave these decisions to the operator, whose practice is tacit, so the fitting stays with the expert. To solve this problem, we proposed to develop a skill for a large language model (LLM) agent via elicitation: the expert's decisions were recorded during fitting and written as thirteen steps and a 22-item report template. The agent runs X-Ray Calc 3 through a Model Context Protocol (MCP) tool server. Fresh sessions, each given the skill, one curve, and a nominal design, were scored against fits the expert had withheld, under six tolerances fixed beforehand. The skill was developed on XRR curves of Co/C mirrors and of Ru/C mirrors from a public data deposit. The final version of the skill was tested on W/B4C multilayers. It was demonstrated that the skill recovered the mean period within 0.3 Å of the expert's fits and the period drift through the stack on both W/B4C specimens, and the W and B4C thicknesses within 1 Å on one of them.

physics.app-ph↗
arXiv2026

Dynamical Diversity for Reservoir Computing in Reconfigurable Nanomechanics

Physical reservoir computing uses nonlinear dynamics and a trained linear readout to process information. Nanoelectromechanical (NEMS) resonators combine geometric Duffing nonlinearity with fading memory, but most electromechanical implementations use a single resonance mode. Here, we demonstrate reservoir computing with two interacting modes of a single NEMS resonator measured through one readout port. We introduce dynamical diversity through complementary modal drive settings: the same input sequence is replayed under different allocations of drive amplitude between the modes, and the responses are concatenated into a single feature matrix. This multiplexing expands the representation available to the readout without additional devices or training of internal parameters. On NARMA-2, it reduces variance-normalized test error more than 28-fold relative to single-mode operation and more than threefold relative to the best individual two-mode setting. Linear memory-capacity measurements show that accessible recall spans only a few symbols at the tested symbol duration. Its rapid decline with delay, consistent with mechanical dissipation, accompanies rising NARMA error and the eventual loss of multiplexing gains at higher orders. We also use electrical feedthrough as an internal reference for assessing the computational contribution of the NEMS response. Separate linear readouts are trained on feedthrough features and features derived from the measured NEMS response, using the same recordings and matched drive settings and processing. On challenging nonlinear mapping tasks, the multiplexed NEMS features yield substantially lower errors than the feedthrough features. These results demonstrate how dynamical diversity through variations in modal drive amplitudes expands the computational capability of a single multimode NEMS resonator.

physics.app-ph↗