Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 2301.04500

Mass-ratio dependent strong-field dissociation of artificial helium hydride isotopologues

Florian Oppermann·Saurabh Mhatre·Stefanie Gräfe·Manfred Lein
View original source ↗Read source document ↗Export metadata ↓

Abstract

We study the effect of the nuclear-mass ratio in a diatomic molecular ion on the dissociation dynamics in strong infrared laser pulses. A molecular ion is a charged system, in which the dipole moment depends on the reference point and therefore on the position of the nuclear center of mass, so that the laser-induced dynamics is expected to depend on the mass asymmetry. Whereas usually both the reduced mass and the mass ratio are varied when different isotopologues are compared, we fix the reduced mass and artificially vary the mass ratio in a model system. This allows us to separate effects related to changes in the resonance frequency, which is determined by the reduced mass, from those that arise due to the mass asymmetry. Numerical solutions of the time-dependent Schrödinger equation are compared with classical trajectory simulations. We find that at a certain mass ratio, vibrational excitation is strongly suppressed, which decreases the dissociation probability by many orders of magnitude.

Explore related subjects

physics.atom-ph

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Florian Oppermann, Saurabh Mhatre, Stefanie Gräfe, Manfred Lein. 2023-02-26. Mass-ratio dependent strong-field dissociation of artificial helium hydride isotopologues. https://doi.org/10.1088/1361-6455%2Faccb75

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

State-Dependent Diffusion and Spectra of Strongly Driven Thermal Atoms

We propose a state-dependent diffusion model for strongly driven thermal-atom spectra. Starting from the trajectory-dependent internal-state evolution of individual atoms, we derive a closed spatial equation for the local density-matrix field using a velocity-moment expansion. Measurements of an $^{85}$Rb atomic-filter transmission spectrum agree well with the model up to a maximum Gaussian peak intensity of $1.27\times10^{3}$ W/cm$^2$, approaching six orders of magnitude above the $^{85}$Rb D2-line saturation intensity. Counterintuitively, the model reveals an anomalous optical-pumping pathway in which intense light transfers atoms from nominally dark states into bright states. Hyperfine Paschen--Back splitting selectively enhances this anomalous pathway while suppressing conventional optical pumping, allowing the filter to maintain approximately 97$\%$ transmission at the highest intensity studied. This work provides a framework for controlling strongly driven atomic ensembles and designing saturation-resistant atomic optical devices.

physics.atom-ph↗
arXiv2026

Interactions and excitation blockade of Rydberg macrodimers

We present a theoretical study of interactions between Rydberg macrodimers, molecular bound states of Rydberg atoms, and the largest known neutral homonuclear diatomic molecules. Accounting for the large number of molecular interaction channels from four interacting Rydberg atoms, we show that macrodimer-macrodimer interactions are anisotropic and similar in strength and range to atomic-state Rydberg interactions. Our analysis reveals the presence of two-atom, three-atom, and four-atom contributions in the bimolecular system, and elucidates how these interactions are rooted in the underlying atomic Rydberg-state couplings. Our calculations of the excitation blockade between macrodimers are in reasonable agreement with experimentally observed signals, and pave the way for the exploration of optically controlled collective quantum dynamics in molecular systems.

physics.atom-ph↗
arXiv2026

Non-orthogonal extension of Graspg - dynamic electron correlation for large and compact active spaces

Accurate relativistic multiconfiguration calculations of correlation-sensitive atomic properties are often limited by the rapid growth of configuration state function expansions when a single common orthonormal orbital basis is used. In this work, a partitioned correlation function interaction (PCFI) method is developed for relativistic atomic structure calculations. The correlation space is separated into physically motivated components, which are optimized independently with correlation-specific orbital sets. The interactions between configuration spaces constructed from mutually non-orthogonal orbital sets are evaluated using biorthonormal transformations, allowing different correlation effects to be combined in a compact final interaction calculation. Full details of the method are provided, emphasizing its connection to configuration state function generators (CSFGs), which significantly reduce the time required to construct the Hamiltonian matrix in conventional RCI calculations. Applications to the neutral Li, Be, and Al atoms are presented for energy levels, mass shifts and hyperfine structure constants. Compared with conventional relativistic configuration interaction (RCI) calculations that rely on a single orbital basis, PCFI produces more compact and predictable convergence patterns for both total and transition energies. It also offers greater stability for correlation-sensitive properties such as specific mass shifts and hyperfine constants. By using property-oriented partitions, PCFI captures core-polarization effects more effectively, thereby reducing the oscillatory behavior often observed in standard RCI approaches. Overall, the results demonstrate that PCFI provides a promising and computationally efficient framework for accurate relativistic multiconfiguration calculations of correlation-dependent atomic properties.

physics.atom-ph↗