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arXiv · 2401.09194

The Zero-Quantum-Defect Method and the Fundamental Vibrational Interval of H$_2^+$

Ioana Doran·Nicolas Hölsch·Maximilian Beyer·Frédéric Merkt
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Abstract

The fundamental vibrational interval of H$_{2}^+$ has been determined to be $\Delta G _{1/2} = 2191.126\,614(17)$ cm$^{-1}$ by continuous-wave laser spectroscopy of Stark manifolds of Rydberg states of H$_2$ with the H$_{2}^+$ ion core in the ground and first vibrationally excited states. Extrapolation of the Stark shifts to zero field yields the zero-quantum-defect positions $-R_{\textrm{H}_2}$/$n^2$, from which ionization energies can be determined. Our new result represents a four-order-of-magnitude improvement compared to earlier measurements. It agrees, within the experimental uncertainty, with the value of 2191.126\,626\,344(17)(100) cm$^{-1}$ determined in non-relativistic quantum electrodynamic calculations V. Korobov, L. Hilico and J.-Ph. Karr, Phys. Rev. Lett. 118, 233001 (2017) http://doi.org/10.1103/PhysRevLett.118.233001.

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Ioana Doran, Nicolas Hölsch, Maximilian Beyer, Frédéric Merkt. 2024-01-17. The Zero-Quantum-Defect Method and the Fundamental Vibrational Interval of H$_2^+$. https://arxiv.org/abs/2401.09194

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