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arXiv · 2410.16994

Properties of an organic model $S=1$ Haldane chain system

Ivan Jakovac·Tonči Cvitanić·Denis Arčon·Mirta Herak·Dominik Cinčić·Nea Baus Topić·Yuko Hosokoshi·Toshio Ono·Ken Iwashita·Nobuyuki Hayashi·Naoki Amaya·Akira Matsuo·Koichi Kindo·Ivor Lončarić·Mladen Horvatić·Masashi Takigawa·Mihael S. Grbić
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Abstract

We present the properties of a new organic $S=1$ antiferromagnetic chain system $m$-NO$_2$PhBNO (abbreviated BoNO). In this biradical system two unpaired electrons from aminoxyl groups are strongly ferromagnetically coupled ($|J_\text{FM}| /k_B \gtrsim 500$ K) which leads to the formation of an effective $S=1$ state for each molecule. The chains of BoNO biradicals propagate along the crystallographic $a$ axis. Temperature dependence of the $g$ factor and electron paramagnetic resonance (EPR) linewidth are consistent with a low-dimensional system with antiferromagnetic interactions. The EPR data further suggest that BoNO is the first known Haldane system with an almost isotropic $g$ factor ($2.0023 \pm 2 \unicode{x2030}$). The magnetization measurements in magnetic fields up to $40$ T and low-field susceptibility, together with $^1$H nuclear magnetic resonance (NMR) spectra, reveal a dominant intrachain antiferromagnetic exchange coupling of $J_\text{1D}/k_B = (11.3\pm0.1)$ K, and attainable critical magnetic fields of $μ_0 H_\text{c1} \approx 2$ T and $μ_0 H_\text{c2} \approx 33$ T. These measurements therefore suggest that BoNO is a unique Haldane system with extremely small magnetic anisotropy. Present results are crucial for a future in-depth NMR study of the low-temperature Tomonaga-Luttinger liquid (TLL) and magnetic field-induced phases, which can be performed in the entire phase space.

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Ivan Jakovac, Tonči Cvitanić, Denis Arčon, Mirta Herak, Dominik Cinčić, Nea Baus Topić, Yuko Hosokoshi, Toshio Ono, Ken Iwashita, Nobuyuki Hayashi, Naoki Amaya, Akira Matsuo, Koichi Kindo, Ivor Lončarić, Mladen Horvatić, Masashi Takigawa, Mihael S. Grbić. 2024-12-24. Properties of an organic model $S=1$ Haldane chain system. https://doi.org/10.1103/physrevb.111.064407

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