Hamiltonian Heat Baths, Coarse-Graining and Irreversibility: A Microscopic Dynamical Entropy from Classical Mechanics

Abstract

The Hamiltonian evolution of an isolated classical system is reversible, yet the second law of thermodynamics states that its entropy can only increase. This has confounded attempts to identify a `Microscopic Dynamical Entropy' (MDE), by which we mean an entropy computable from the system's evolving phase-space density $ρ(t)$, that equates {\em quantitatively} to its thermodynamic entropy $S^{\rm th}(t)$, both within and beyond equilibrium. Specifically, under Hamiltonian dynamics the Gibbs entropy of $ρ$ is conserved in time; those of coarse-grained approximants to $ρ$ show a second law but remain quantitatively unrelated to heat flow. Moreover coarse-graining generally destroys the Hamiltonian evolution, giving paradoxical predictions when $ρ(t)$ exactly rewinds, as it does after velocity-reversal. Here we derive the MDE for an isolated system XY in which subsystem Y acts as a heat bath for subsystem X. We allow $ρ_{XY}(t)$ to evolve without coarse-graining, but compute its entropy by disregarding the detailed structure of $ρ_{Y|X}$. The Gibbs entropy of the resulting phase-space density $\tildeρ_{XY}(t)$ comprises the MDE for the purposes of both classical and stochastic thermodynamics. The MDE obeys the second law whenever $ρ_X$ evolves independently of the details of Y, yet correctly rewinds after velocity-reversal of the full XY system.