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arXiv · 2503.16765

A thermodynamically consistent phase-field model for mass transport with interfacial reaction and deformation

Zhaoyang Wang·Huaxiong Huang·Ping Lin·Shixin Xu
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Abstract

In this paper, a thermodynamically consistent phase-field model is proposed to describe the mass transport and reaction processes of multiple species in a fluid. A key feature of this model is that reactions between different species occur only at the interface, and may induce deformation of the interface. For the governing equations derived based on the energy variational method, we propose a structure-preserving numerical scheme that satisfies the mass conservation and energy dissipation laws at the discrete level. Furthermore, we carry out a rigorous error analysis of the time-discrete scheme for a simplified case. A series of numerical experiments are conducted to validate the effectiveness of the model as well as the accuracy and stability of the scheme. In particular, we simulate microvessels with straight and bifurcated structures to illustrate the risk of microaneurysm formation.

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Zhaoyang Wang, Huaxiong Huang, Ping Lin, Shixin Xu. 2025-03-21. A thermodynamically consistent phase-field model for mass transport with interfacial reaction and deformation. https://arxiv.org/abs/2503.16765

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