Incoherent population trapping in quantum emitters

Abstract

Deterministic emitters transform electronic excitations to photons with unity efficiency. Their development is crucial for both energy-efficient optical interconnects and photonic quantum technologies, but neither rigorous theoretical frameworks nor systematic experimental methods governing deterministic emitters and their identification were so far available. A central -- and seemingly obvious -- assumption underpinning previous works is that the radiative emission probability is proportional to the internal quantum efficiency. Here, we introduce a stochastic model of the decay dynamics in quantum emitters that disproves this assumption and provides a systematic framework for the development of deterministic quantum light sources. Our model agrees with a wide range of experimental findings, including time-resolved spectroscopy, autocorrelation measurements, and saturation spectroscopy, and it also explains a number of hitherto unexplained experiments. For example, our model shows that above-band continuous-wave excitation selects the exciton transitions with the lowest quantum efficiency, which is of direct importance for photonic quantum technologies relying on aligning nanostructures to emitters. We show that the underlying physics is governed by incoherent trapping of the population in metastable states, which has profound consequences for the physics of quantum emitters. Finally, we provide a straightforward experimental protocol for obtaining deterministic emitters.