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arXiv · 2509.03146

Hierarchically structured, high-efficiency and thermally robust perovskite solar cells with band-engineered double-hole layers

Md. Faiaad Rahman·Arpan Sur·Ahmed Zubair
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Abstract

Despite the promising optoelectronic properties of methylammonium lead iodide (MAPbI3)-based perovskite solar cells (PSCs), their commercial viability is hindered by interfacial energy misalignment, suboptimal light absorption, and thermal instability. Here, we present a comprehensive theoretical framework to enhance the power conversion efficiency (PCE) of MAPbI3 based PSC through integrated electronic and morphological engineering. Firstly, to address interfacial recombination and inefficient hole extraction at the perovskite/HTL junction, we introduced a double hole transport layer (HTL) stack comprising CuO and I2O5-doped Spiro-OMeTAD, which significantly improved energy level alignment and carrier selectivity. Comprehensive multiphysics simulations, combining finite-difference time-domain (FDTD) optical analysis with finite element method (FEM) based electrical and thermal modeling, demonstrated that optimized doping concentrations and thickness parameters within the CuO/Spiro-OMeTAD hole transport layers can enhance the PCE to 22.78%. However, planar architectures, while offering ease of fabrication and scalability, exhibit weak near-UV and near-infrared absorption, whereas nanostructures attain superior light trapping but incur significant fabrication complexity, underscoring the need for balanced design strategies. To address these inherent limitations, we propose a hierarchical ellipsoidal patterned solar cell (HEPSC), wherein a top-layer ellipsoidal nanostructure is introduced across the full device stack. This design enhances broadband light trapping and optical confinement throughout the active layers while maintaining fabrication feasibility through geometrically realistic structuring.

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Md. Faiaad Rahman, Arpan Sur, Ahmed Zubair. 2025-09-03. Hierarchically structured, high-efficiency and thermally robust perovskite solar cells with band-engineered double-hole layers. https://arxiv.org/abs/2509.03146

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