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arXiv · 2510.13513

Magnetomechanical Coupling in Ferronematic Phases: Influence of Spindle-Shaped Nanodopants on Liquid Crystalline Order

Karin Koch·Joachim Landers·Damian Günzing·Hajnalka Nádasi·Heiko Wende·Alexey Eremin·Annette M. Schmidt
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Abstract

Ferronematic phases, composed of liquid crystals doped with magnetic nanoparticles, exhibit unique magnetomechanical coupling effects that are of interest for responsive materials. In this study, we investigate the influence of spindle-shaped α-Fe_2O_3 nanoparticles functionalized with a mesogen-decorated polymer brush on the phase behavior and field-induced transitions of a nematic host (5CB). Differential scanning calorimetry (DSC), refractometry, and dielectric spectroscopy reveal a non-monotonic dependence of the nematic-isotropic transition temperature on particle concentration, indicating a competition between stabilizing and destabilizing effects. The order parameter increases with increasing nanoparticle content, in contrast to non-magnetic reference systems, suggesting an alignment effect induced by the magnetic rather than the geometric anisotropy axis of the dopants. Capacitance measurements of the Freedericksz transition show a pronounced shift in threshold fields, with a critical concentration marking a transition to enhanced magnetic responsiveness. Additional information on nanospindle diffusion correlated to the direction-dependent flow of the nematic host was inferred from comparison of Moessbauer spectroscopy and rheology data. Our findings provide insights into the interplay of magnetic and geometric anisotropy in ferronematic systems and highlight their potential for applications in tunable soft matter devices.

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Karin Koch, Joachim Landers, Damian Günzing, Hajnalka Nádasi, Heiko Wende, Alexey Eremin, Annette M. Schmidt. 2025-10-15. Magnetomechanical Coupling in Ferronematic Phases: Influence of Spindle-Shaped Nanodopants on Liquid Crystalline Order. https://arxiv.org/abs/2510.13513

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