Rippled Moire Superlattices for Decoupled Ferroelectric Bits

Abstract

Symmetry considerations suggest that moire superlattices formed by twisted two-dimensional materials should preserve overall inversion symmetry. However, experiments consistently report robust ferroelectricity in systems such as twisted bilayer h-BN, posing a fundamental discrepancy between theory and experiment regarding its microscopic origin. Here, using large-scale finite-field molecular dynamics simulations, we challenge the prevailing defect-pinning hypothesis and instead identify an out-of-plane bending field, induced by in-plane compressive strain, as the key symmetry-breaking mechanism. This strain-induced rippling drives spatially heterogeneous interlayer sliding and distorts the moire domain wall network, resulting in a four-state ferroelectric system. Remarkably, we show this mechanism can be harnessed at the nanoscale, where localized nanobubbles designate the moire lattice's fundamental hexagonal domain clusters as the smallest individually addressable ferroelectric bits, thereby imposing local control on an otherwise globally defined structure. Our findings establish a geometry-driven framework for understanding and engineering moire ferroelectrics, offering not only a route toward ultra-high-density, rewritable memory, but also a strategy for locally tuning the moire potential itself, a critical step for manipulating emergent correlated and topological quantum phases.