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arXiv · 2511.03199

Exploring the mechanisms of transverse relaxation of copper(II)-phthalocyanine spin qubits

Boning Li·Yifan Quan·Xufan Li·Guoqing Wang·Robert G Griffin·Avetik R Harutyunyan·Paola Cappellaro
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Abstract

Molecular spin qubits are promising candidates for quantum technologies, but their performance is limited by decoherence arising from diverse mechanisms. The complexity of the environment makes it challenging to identify the main source of noise and target it for mitigation. Here we present a systematic experimental and theoretical framework for analyzing the mechanisms of transverse relaxation in copper(II) phthalocyanine (CuPc) diluted into diamagnetic phthalocyanine hosts. Using pulsed EPR spectroscopy together with first-principles cluster correlation expansion simulations, we quantitatively separate the contributions from hyperfine-coupled nuclear spins, spin--lattice relaxation, and electron--electron dipolar interactions. Our detailed modeling shows that both strongly and weakly coupled nuclei contribute negligibly to $T_2$, while longitudinal dipolar interactions with electronic spins, through instantaneous and spectral diffusion, constitute the main decoherence channel even at moderate spin densities. This conclusion is validated by direct comparison between simulated spin-echo dynamics and experimental data. By providing a robust modeling and experimental approach, our work identifies favorable values of the electron spin density for quantum applications, and provides a transferable methodology for predicting ensemble coherence times. These insights will guide the design and optimization of molecular spin qubits for scalable quantum devices.

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Boning Li, Yifan Quan, Xufan Li, Guoqing Wang, Robert G Griffin, Avetik R Harutyunyan, Paola Cappellaro. 2025-11-05. Exploring the mechanisms of transverse relaxation of copper(II)-phthalocyanine spin qubits. https://arxiv.org/abs/2511.03199

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