Spreading dynamics of drops on a solid surface submerged in different outer fluids

Abstract

Hypothesis: Surrounding fluids affect critically drop wetting dynamics in many applications involving viscous environments. Although macroscopic effects of outer fluid viscosity on contact line motion have been documented, the extent to which the outer fluid modulates internal flow pattern is still not well understood, largely due to experimental challenges. It is hypothesized that the external fluid exerts a dominant effect on the internal flow fields and energy dissipation, thereby altering dynamic contact angle evolution and overall wetting behavior. Elucidating this coupling mechanism is essential for advancing our understanding of multiphase spreading in complex fluid systems. Experiments: We investigate the spreading of Newtonian and non-Newtonian shear-thinning aqueous drops in air versus in oil, using high-speed imaging and custom-built micro-PIV. Internal velocity and viscosity fields are measured to quantitatively relate internal flow evolution to contact line motion. Dynamic contact angle was measured and analyzed using composite model incorporating hysteresis and pinning. Scaling laws were derived to compare spreading dynamics under different outer fluid viscosities and substrate wettabilities. Findings: In air, capillary waves trigger Laplace pressure gradients that drive rapid, outward internal flow as well as fast contact line motion. In contrast, viscous oils suppress wave formation and generate recirculating vortices, resulting in a significantly slower spreading process dominated by viscous drag. Despite power-law spreading in both cases, the governing timescales reflect fundamentally different mechanisms: inertial forces within the drop dominate in air, whereas external fluid viscosity controls the spreading dynamics in oil. A unified scaling incorporating outer-fluid viscosity and equilibrium contact angle gathers diverse data onto a master curve. These results underscore the central role played by outer-fluid induced internal flow in governing wetting dynamics.