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arXiv · 2512.12584

Extended dissipaton theory for higher-order bath couplings and application to non-Condon spectroscopy with anharmonicity

Zi-Fan Zhu·Yu Su·Yao Wang·Rui-Xue Xu·YiJing Yan
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Abstract

In this work, we develop an extended dissipaton theory that generalizes the environmental couplings beyond the conventional linear and quadratic forms, enabling the treatment of arbitrary order of bath couplings. Applying this theoretical framework to the condensed-phase non-Condon spectroscopy, we demonstrate the interplay of anharmonicity, non-Condon and solvent effects on optical spectra. Precise simulations are carried out with high efficiency on linear absorption spectra involving the above mentioned correlated effects. We exhibit how an anharmonic potential modulates the vibronic feature, offering insights into the role of nonlinear environmental couplings in spectroscopic signatures and exemplifying the success of the extended dissipaton formalism as an exact and efficient method for higher-order bath couplings.

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Zi-Fan Zhu, Yu Su, Yao Wang, Rui-Xue Xu, YiJing Yan. 2025-12-14. Extended dissipaton theory for higher-order bath couplings and application to non-Condon spectroscopy with anharmonicity. https://arxiv.org/abs/2512.12584

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