A comparison of different image analysis techniques for mapping spatiotemporal pH and carbon dissolution in density-driven convection of CO2 in water

Abstract

Density-driven convection enhances the carbon dissolution rate, which is significant for the geological carbon storage. This process will also influence the spatiotemporal pH and carbon concentrations of the underground fluid. To illuminate the convection mechanism, it is critical to understand the evolution of those properties within the porous media. However, determining the spatiotemporal pH and concentration within porous media is always challenging. This study employed a combination of three pH indicators that can track a wide range in pH from 4 to 9.5 in a convection experiment. Furthermore, we compared three image-processing techniques: Hue, gray-difference, and angular representation of RGB color space $\mathbf{(ϕ,θ)}$ for quantifying color changes from the universal $\text{pH}$ indicator arising from the carbon convection. The characterized colors were mapped into pH by calibrating against benchmark solutions. The comparative results demonstrate that the color quantified by the Hue technique is most robust, showing invariance to fluid thickness, camera settings, and LED luminance. In the convection experiments, it produces a continuous spatial distribution of pH and concentration level in the system. In contrast, the $\mathbf{(ϕ,θ)}$ and gray-difference techniques were more sensitive to environmental variations. They also have significant limitations for $\text{pH}$ interpolation in the critical range due to their non-monotonic calibration paths. Although all methods ultimately produced similar estimates of total dissolved carbon, the Hue technique offers greater stability and universality for high-resolution, dynamic measurements of pH and carbon concentration in the convection experiments.