Following the thread: surface and bulk solvent migration in silicone elastomers from local volumetric swelling

Chenzhuo Li; Tom Beyeler; Marc Antonio Chalhoub; John M. Kolinski

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arXiv · 2605.12125

Following the thread: surface and bulk solvent migration in silicone elastomers from local volumetric swelling

Chenzhuo Li·Tom Beyeler·Marc Antonio Chalhoub·John M. Kolinski

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Abstract

Poroelastic materials, consisting of a permeable solid matrix infiltrated with fluid, are ubiquitous in natural and engineering contexts. In poroelastic polymer solids, the elastic matrix swells to equilibrium when immersed in a solvent bath; thus, the network elasticity couples to the solvent transport. Despite the ubiquity and importance of poroelastic theory in describing phenomena as diverse as earthquakes and biological tissues, there is a paucity of experimental data that probe the local network response to controlled stress and solvent boundary conditions. Here, we first probe the baseline diffusion kinetics of a polymeric solvent during free swelling of a polydimethylsiloxane (PDMS) network with well-characterized silicone oils. In situ 3D spatiotemporal measurements identify a flux-limited interfacial boundary condition, contradicting the canonical fully drained assumption. This correction eliminates an order-of-magnitude underestimation of diffusivity in standard bulk analysis. The swelling equilibrium is accurately captured by a Flory-Rehner theory that requires modification to include the effective finite extensibility of the filled network. Solvent migration is then studied using a bending configuration for three material preparations: as-prepared, mobile-phase-free, and fully swollen in silicone oils. The as-prepared and mobile-phase-free beams show no discernible volumetric change or force relaxation, whereas local in situ measurements directly resolve tensile-side dilation and compressive-side contraction, yielding the effective diffusivities in agreement with the force-relaxation data. These measurements rigorously benchmark solvent diffusivity in polymer networks, underscoring the importance of unambiguous interfacial boundary conditions and shedding light on mechanics and engineering across poroelastic polymers and geomaterials.

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Chenzhuo Li, Tom Beyeler, Marc Antonio Chalhoub, John M. Kolinski. 2026-05-12. Following the thread: surface and bulk solvent migration in silicone elastomers from local volumetric swelling. https://arxiv.org/abs/2605.12125

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