Thermodynamically consistent modeling of ion exchange membranes in multi-ionic environments

Abstract

Ion exchange membranes are useful for a wide range of applications, including water desalination, fuel cells, and aqueous batteries. Accordingly, a variety of models for ion exchange membranes has been proposed, each emphasizing different aspects that govern their static and dynamic properties. By reviewing these models, we identify key physical contributions and beneficial modeling strategies. Based on these insights, we derive a thermodynamically consistent model by combining mass-action site occupation with mean-field electrostatic interactions along the polymer backbone. In this derivation, we explicitly account for multicomponent electrolytes at elevated concentrations. The parameters of the resulting model relate closely to those of other models, but gain consistency and interpretability through the underlying derivation. A discussion of the model parameters highlights redundancies and linkages between quantities that are commonly treated independently. Comparison to experimental data shows that both static and dynamic membrane properties are reproduced with good accuracy by the presented model. This makes it a promising basis for theory-driven membrane optimization and supports the tailored design of ion exchange membranes for various technologies.