Even-harmonic generation through nonequilibrium steady-state symmetry breaking

Abstract

High-harmonic generation (HHG) in inversion-symmetric systems is typically restricted to odd harmonics by symmetry. Here, we show that this selection rule can be broken without modifying the underlying Hamiltonian. We investigate a boundary-driven Su-Schrieffer-Heeger (SSH) chain coupled to source and sink reservoirs and demonstrate that dissipative dynamics generates a nonequilibrium steady state carrying a finite DC current. While the SSH Hamiltonian retains inversion symmetry, the current-carrying steady-state density matrix does not, leading to the emergence of even harmonics in the emitted spectrum. Using a correlation-matrix approach based on the Lindblad master equation, we obtain the steady state and calculate the resulting HHG response. We find that the intensity of the even harmonics is directly controlled by the transport current, establishing a link between nonequilibrium charge transport and HHG selection rules. Our results uncover a mechanism for even-harmonic generation that relies solely on nonequilibrium steady-state symmetry breaking and provide a route to probing transport currents through ultrafast nonlinear spectroscopy in centrosymmetric quantum systems.