Search arXiv⌕ Search

arXiv · 2610.30749

Strain Waves Generate Compression and Trigger Buckling in Active Polymers

Abstract

Chemical reactions can sustain polymer motion without necessarily generating the compression required for buckling. Theory and simulations show that tension-dependent chemical transitions coupled to bond elasticity generate finite-wavelength traveling strain waves in a semiflexible polymer. In the straight chain at fixed axial span, the waves reduce mean active contraction while leaving mean elastic tension unchanged, generating compression that drives bending above a threshold. Releasing the mean load allows longitudinal waves to persist while transverse perturbations decay.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Wen-de Tian, Kang Chen, Tianhui Zhang. 2026-10-22. Strain Waves Generate Compression and Trigger Buckling in Active Polymers. https://arxiv.org/abs/2610.30749

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Emergent Entropic Forces Drive Inverse and Reentrant Phase Transitions in Condensates of Intrinsically Disordered Proteins

We present a phenomenological, mean-field model for condensates of intrinsically disordered proteins that describes inverse phase transitions and qualitatively predicts reentrant phase behavior as a function of salt concentration. The model is based on a matrix-based formulation of the Flory-Huggins free energy, in which the enthalpic interaction parameter and the protein valence, defined here as the number of effective "sticky patches", are treated as free parameters. Its central insight is that integrating out dynamics of fast-moving molecular species generates an effective entropic force that increases the free-energy barrier to mixing, even within a mean-field description. We account for this by linking Gaussian integration of co-solutes to the Schur complement of the matrix-based Flory-Huggins free energy. This provides a general thermodynamic framework illustrating how enthalpic interactions that increase the number of available microstates necessarily induce effective entropic forces. We demonstrate the expressiveness and predictive power of the model by qualitatively reproducing recent experimental observations on the rabies virus phosphoprotein.

cond-mat.soft↗

Entropy-production cost limits hierarchical decision-making in homing pigeon flocks

Collective decision-making requires individuals to reconcile diverse, often conflicting opinions to reach a common course of action. However, within a group, they rarely exert equal influence, leading to non-reciprocal communication patterns manifested as leader-follower relationships and social hierarchies. Here, using homing pigeon flocks as a model system, we develop a trajectory-based framework to infer and quantify hierarchy within navigating living collectives. We find that while small flocks exhibit pronounced hierarchy, increasing flock size progressively weakens it, driving the collection toward more egalitarian decision-making. We provide a physical basis of this observation using a thermodynamic framework in which non-reciprocal communication between birds carries an information-entropy cost. Our calculations reveal that hierarchy weakening observed in larger flocks is a direct consequence of maintaining a constant per-individual entropy production rate across flock sizes. Together, these results suggest that constraints on information-processing capacity may play an important role in the collective dynamics of living organisms.

cond-mat.soft↗

Functional understanding of structural components in polypseudorotaxane gels

Biomedical devices, wearable interfaces, and soft robots require compliant soft materials with reliable mechanical performance, yet the molecular principles needed to design such materials are not always fully understood. Thus, there is an urgent need to understand how to design novel stretchable and soft hydrogels with enhanced toughness, i.e. resistance to breakage. Slide-ring gels (SRGs) are a class of unconventional soft materials formed by polyrotaxanes (PR) building blocks whereby sliding cyclodextrins (CD) replace traditional chemical and physical crosslinks and in turn enhance toughness and stretchability by several orders of magnitude. The rational design of SRGs re- mains challenging due to a lack of a mechanistic understanding of the role played by individual components. In this work, we implement simple synthetic perturbations that individually target polymer-CD and CD-CD interactions in unstoppered pseudopolyrotaxanes (pPR) solutions and measure the consequent changes in viscoelastic properties. Weakening the intermolecular interaction between CDs abolishes crystallisation and significantly weakens the gel. At the same time, thermodynamically favouring threading by using azobenzene-modified PEG chains favours the formation of stable and long-lived networks even at remarkably low CD stoichiometries. We rationalise these observations with coarse-grained Molecular Dynamics simulations which clarify the structure-function relationship of the components forming these materials. Our work contributes to guiding the rational design and development of enhanced SRG hydrogels and elastomers.

cond-mat.soft↗